Journal ArticleDOI
Flame retardancy of poly(styrene-co-acrylonitrile) by the synergistic interaction between clay and phosphomolybdate hydrates ☆
TLDR
In this paper, a combination of montmorillonite (MT) clay and catalysts was used to explore possible synergistic effects in reducing the flammability of poly(styrene-co-acrylonitrile) (SAN).About:
This article is published in Polymer Degradation and Stability.The article was published on 2011-05-01. It has received 14 citations till now. The article focuses on the topics: Ammonium phosphomolybdate & Char.read more
Citations
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Journal ArticleDOI
Engineering biodegradable polymer blends containing flame retardant-coated starch/nanoparticles
Seongchan Pack,Ezra Bobo,Neil Muir,Kai Yang,Sufal Swaraj,Harald Ade,Changhong Cao,Chad S. Korach,Takashi Kashiwagi,Miriam Rafailovich +9 more
TL;DR: In this article, the authors examined the effect of RDP-coated starch on thermal responses of a blend of Ecoflex/PLA and found that the addition of resorcinol di(phenyl phosphate) (RDP)-coated starchy can improve the compatibility to either Ecoflex or poly(lactic acid) (PLA).
Journal ArticleDOI
Influence of Ionic Liquid-Based Metal–Organic Hybrid on Thermal Degradation, Flame Retardancy, and Smoke Suppression Properties of Epoxy Resin Composites
TL;DR: In this paper, a new multifunctional ionic liquid-based metal-organic hybrid (PMAIL) was synthesized by anion exchange between as-synthesized phosphonate-based Ionic liquid and phosphomolybdic acid and applied to epoxy resin (EP) as an efficient flame retardant.
Journal ArticleDOI
Synergistic effect of expanded graphite, diammonium phosphate and Cloisite 15A on flame retardant properties of EVA and EVA/wax phase-change blends
TL;DR: In this article, the influence of expanded graphite (EG), as well as combinations of EG with Cloisite 15A clay and diammonium phosphate (DAP), into EVA and an EVA/wax blend was investigated.
Journal ArticleDOI
Extended light absorption and enhanced visible-light photocatalytic degradation capacity of phosphotungstate/polyimide photocatalyst based on intense interfacial interaction and alternate stacking structure
TL;DR: In this article, a novel phosphotungstate/polyimide photocatalyst (MPWPI) was constructed via in situ solid-state thermal polymerization using melamine and water-soluble triazine melamine.
Journal ArticleDOI
Roles of supermolecule structure of melamine phosphomolybdate in intumescent flame retardant polypropylene composites
TL;DR: In this paper, the supermolecular structure of melamine phosphomolybdate (MAPMo) was tailored by changing the ratio of MA/PMo, which increased the thermal stability of MA and had a great effect on flame retardant efficiency.
References
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Journal ArticleDOI
Kinetic analysis of the thermal degradation of polystyrene–montmorillonite nanocomposite
TL;DR: In this article, a polystyrene (PS) clay nanocomposite was prepared via bulk polymerization using a novel organically modified montmorillonite (MMT), the organic-modifier is the N,N-dimethyl-nhexadecyl-(4-vinylbenzyl) ammonium chloride (VB16), the thermal stability of PS-VB16 compared to pure PS is examined in pyrolytic and thermo-oxidative conditions.
Journal ArticleDOI
Relation between the viscoelastic and flammability properties of polymer nanocomposites
Takashi Kashiwagi,Minfang Mu,Karen I. Winey,Bani H. Cipriano,Srinivasa R. Raghavan,Seongchan Pack,Miriam Rafailovich,Yin Yang,Eric A. Grulke,John R. Shields,Richard H. Harris,Jack F. Douglas +11 more
TL;DR: In this paper, the formation of a network structure of nanoparticles within a polymer matrix can significantly reduce nanocomposite flammability and that viscoelastic properties could be utilized to predict their flammable reduction.
Journal ArticleDOI
Polymer combustion and flammability—Role of the condensed phase∘
TL;DR: In this article, the effects of polymer characteristics on combustion and flammability are not nearly as well understood as those in the gas phase, and a nonhalogenated char-forming flame-retardant approach is suggested to improve the fire performance of polymers.
Journal ArticleDOI
Synergistic effects of silicotungistic acid on intumescent flame-retardant polypropylene
TL;DR: In this article, the synergistic effects of silicotungistic acid (SiW12) as a catalyst in polypropylene (PP) flame-retarded by the intumescent flame retarder (IFR) based on the NP28 phosphorus-nitrogen compound were studied using the limiting oxygen index (LOI), the UL-94 test, thermogravimetric analysis (TGA), real time Fourier transform infrared (FTIR), laser Raman spectroscopy (LRS), and scanning electron microscopy (SEM).
Journal ArticleDOI
Ethylene vinyl acetate/layered silicate nanocomposites prepared by a surfactant-free method: Enhanced flame retardant and mechanical properties
Yaru Shi,Takashi Kashiwagi,Richard N. Walters,Jeffrey W. Gilman,Richard E. Lyon,Dotsevi Y. Sogah +5 more
TL;DR: Exfoliated EVA/layered silicate nanocomposites were prepared by a masterbatch process using polymer-modified layered silicate instead of small molecule surfactant-modified clays as mentioned in this paper.
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Synergistic catalysis effects of lanthanum oxide in polypropylene/magnesium hydroxide flame retarded system
Lei Shen,Yinghong Chen,Pingli Li +2 more