Journal ArticleDOI
Formation mechanism, electronic properties & microwave shielding by nano-structured polyanilines prepared by template free route using surfactant dopants
Parveen Saini,Manju Arora +1 more
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TLDR
In this paper, a detailed correlation between acquired morphology, structural, spectral, electrical and EM properties of the polyaniline (PANI) nanostructures synthesized by a template free route using surfactant dopants as structure directing agents is reported.Abstract:
Conducting polymers are at the forefront of nanomaterial's research but the fundamental mechanisms that govern the formation of functional nanostructures and control their electromagnetic (EM) properties are still unknown. Herein, we report for the first time a detailed correlation between acquired morphology, structural, spectral, electrical and EM properties of the polyaniline (PANI) nanostructures synthesized by a template free route using surfactant dopants as structure directing agents. Aniline has been emulsion polymerized in the presence of different sulfonic acids viz. dodecylbenzenesulfonic acid, camphorsulfonic acid, ligninsulfonic acid & cardanolazophenylsulfonic acid and the formed PANIs have been designated as PDB, PCS, PLS and PCD, respectively. The SEM investigations revealed that the morphology is critically dependent on the nature of the dopant, while FTIR, XRD, EPR and UV-visible studies revealed that doping level follows the order PCD 99.999% of incident EM radiation) demonstrate the potential of these materials for making future microwave shields.read more
Citations
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Ultrathin graphene: electrical properties and highly efficient electromagnetic interference shielding
TL;DR: In this article, a review of the advance in graphene-based EMI shielding materials is presented, where the authors intensively evaluate the mechanism, such as polarization, hopping conduction and interface scattering.
Journal ArticleDOI
Magnetic graphene@PANI@porous TiO2 ternary composites for high-performance electromagnetic wave absorption
TL;DR: A two-step strategy combining in situ polymerization and a hydrothermal process has been developed for coupling polyaniline (PANI) with porous TiO2 anchored on magnetic graphene as mentioned in this paper.
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Cellulose composite aerogel for highly efficient electromagnetic interference shielding
TL;DR: In this article, an ultra-light and highly conductive cellulose composite aerogel was fabricated by a simple, efficient and environmentally benign strategy; the scaffold structure was well designed from nanofibrillar networks to nanosheet networks by controlling the concentration of cellulose in the sodium hydroxide/urea solution.
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Naturally occurring phenolic sources: monomers and polymers
TL;DR: In this article, a review article is designed to acknowledge efforts of researchers towards the 3C motto, not only trying to create but also adapting the principles to conserve and care for a sustainable environment.
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Stretchable and conductive polymer films for high-performance electromagnetic interference shielding
TL;DR: In this paper, highly conductive and stretchable polymer films were prepared by blending a conductive polymer, poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS), with highly stretchable waterborne polyurethane (WPU).
References
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A. M. Nicolson,G. F. Ross +1 more
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Automatic measurement of complex dielectric constant and permeability at microwave frequencies
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Counter-ion induced processibility of conducting polyaniline and of conducting polyblends of polyaniline in bulk polymers
TL;DR: In this article, the authors demonstrate the feasibility of processing, in the conducting form, polyaniline and a variety of polyblends made from polyanILine, which can be melt-processed or processed from solution to enable the fabrication of thin films, sheets, fibers, transparent conductive films, bulk parts.
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Electromagnetic interference shielding of graphene/epoxy composites
Jiajie Liang,Yan Wang,Yi Huang,Yanfeng Ma,Zunfeng Liu,Jinming Cai,Chendong Zhang,Hong-Jun Gao,Yongsheng Chen +8 more
TL;DR: In this paper, composites based on graphene-based sheets have been fabricated by incorporating solution-processable functionalized graphene into an epoxy matrix, and their electromagnetic interference (EMI) shielding studies were studied.