Journal ArticleDOI
Formic acid as a hydrogen storage material – development of homogeneous catalysts for selective hydrogen release
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TLDR
From 2010 onwards, this review covers recent advancements in this area using homogeneous catalysts for H2 generation, reversible H2 storage including continuous H2 production from formic acid is highlighted.Abstract:
Formic acid (FA, HCO2H) receives considerable attention as a hydrogen storage material. In this respect, hydrogenation of CO2 to FA and dehydrogenation of FA are crucial reaction steps. In the past decade, for both reactions, several molecularly defined and nanostructured catalysts have been developed and intensively studied. From 2010 onwards, this review covers recent advancements in this area using homogeneous catalysts. In addition to the development of catalysts for H2 generation, reversible H2 storage including continuous H2 production from formic acid is highlighted. Special focus is put on recent progress in non-noble metal catalysts.read more
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State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis.
Qi Wang,Didier Astruc +1 more
TL;DR: This review first briefly summarizes this background of MOF nanoparticle catalysis and then comprehensively reviews the fast-growing literature reported during the last years.
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Homogeneously Catalyzed Electroreduction of Carbon Dioxide-Methods, Mechanisms, and Catalysts
TL;DR: The developments of the last three decades in electrocatalytic CO2 reduction with homogeneous catalysts are reviewed and important catalyst families are discussed in detail with regard to mechanistic aspects, and recent advances in the field are highlighted.
Journal ArticleDOI
Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols.
Katerina Sordakis,Conghui Tang,Lydia K. Vogt,Henrik Junge,Paul J. Dyson,Matthias Beller,Gábor Laurenczy +6 more
TL;DR: In this paper, the authors describe the considerable progress that has been made in homogeneous catalysis for these critical reactions, namely, the hygienic reaction, and describe a review of the most relevant work in this area.
Journal ArticleDOI
Formic Acid as a Hydrogen Energy Carrier
Jörg Eppinger,Kuo-Wei Huang +1 more
TL;DR: In this paper, the authors highlight the advantages of this approach with discussions focused on potential applications in the transportation sector together with analysis of technical requirements, limitations, and costs for selective hydrogen generation from formic acid.
Journal ArticleDOI
Reduced SnO2 Porous Nanowires with a High Density of Grain Boundaries as Catalysts for Efficient Electrochemical CO2 -into-HCOOH Conversion.
Bijandra Kumar,Veerendra Atla,J. Patrick Brian,Sudesh Kumari,Tu Quang Nguyen,Mahendra K. Sunkara,Joshua M. Spurgeon +6 more
TL;DR: It is shown that an electrochemically reduced SnO2 porous nanowire catalyst (Sn-pNWs) with a high density of grain boundaries (GBs) exhibits an energy conversion efficiency of CO2 -into-HCOOH higher than analogous catalysts.
References
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Journal ArticleDOI
Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
Journal ArticleDOI
Hydrogen storage in metal–organic frameworks
TL;DR: This critical review of the current status of hydrogen storage within microporous metal-organic frameworks provides an overview of the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity.
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