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Hardening evolution of geopolymers from setting to equilibrium: A review

TLDR
In this article, a review of known factors that influence the setting time of fresh geopolymers and discusses the underlying chemical and physical-mechanisms of each parameter is discussed.
Abstract
In recent years, environmentally sustainable geopolymers have been widely investigated to obtain comparable mechanical properties with Portland cement, and they are now close to being in a position where they can substitute parts of the cement production utilized in construction. However, in order for geopolymers to reach their full potential, it is crucial to understand the influence of various parameters (e.g., particle size, treatment of precursor, chemical composition) on the hardening evolution at earlier ages of the pastes and the resulting final mechanical strength of the set system. Hence, this paper reviews known factors that influence the setting time of fresh geopolymers and discusses the underlying chemical- and physical-mechanisms of each parameter. Next to this, the interconnection between the setting time and mechanical strength is discussed. This will provide a platform for researchers and engineers to understand the hardening evolution of geopolymers in a broader range.

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Eco-friendly geopolymer materials: A review of performance improvement, potential application and sustainability assessment

TL;DR: In this paper, the authors reviewed the recent research progress on the performance improvement, potential new application and sustainability assessment of geopolymer materials and pointed out some performance optimization methods for geopolymers-based porous materials and 3D printing materials.
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Development of fly ash and slag based high-strength alkali-activated foam concrete

TL;DR: In this paper , the fly ash and slag-based alkali-activated foam concrete with a design density ranging from 200 kg/m3 to 1200 kg/ m3 was developed.
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3D printing geopolymers: A review

TL;DR: A critical review of the state-of-the-art 3D printing geopolymers from the perspectives of production process, printability requirement, mix design, early-age material properties and sustainability, with a special focus on the effects of different factors such as matrix composition, reinforcement type, curing regime and printing configuration on the fresh and hardened properties of 3D printed geo-mers as discussed by the authors .
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Rheological characterization of 3D printable geopolymers

TL;DR: In this article, a two-step approach that enables quantification of concrete printability through dynamics mode rheological measurements is presented. But it is not shown that the shearing history of the material is removed by imposing a pre-shearing above the critical strain and zero value yield stress is measured for all specimens.
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A Comprehensive Review on Fly Ash-Based Geopolymer

TL;DR: In this article , the authors comprehensively review the rheological, strength and durability properties of inorganic geopolymer composites, along with shedding light on their recent key advancements.
References
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Journal ArticleDOI

Geopolymer technology: the current state of the art

TL;DR: A brief history and review of geopolymer technology is presented with the aim of introducing the technology and the vast categories of materials that may be synthesized by alkali activation of aluminosilicates as mentioned in this paper.
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Geopolymers : inorganic polymeric new materials

TL;DR: In the last few years, technological progress has been made in the development of new materials such as "geopolymers" and new techniques, such as ''sol-gel'' as mentioned in this paper, opening up new applications and procedures and transforming ideas that have been taken for granted in inorganic chemistry.
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Industrially interesting approaches to “low-CO2” cements ☆

TL;DR: In this paper, the authors discuss the practicality of replacing portland cements with alternative hydraulic cements that could result in lower total CO 2 emissions per unit volume of concrete of equivalent performance.
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The geopolymerisation of alumino-silicate minerals

TL;DR: In this paper, the effect of mineral properties on the compressive strength of the synthesized geopolymer was investigated, and it was shown that a wide range of natural Al-Si minerals could serve as potential source materials for the synthesis of geopolymers.
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