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High-yield synthesis of uniform Ag nanowires with high aspect ratios by introducing the long-chain PVP in an improved polyol process

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TLDR
In this article, a polyvinyl pyrrolidone (PVP) with different molecular weights was used as capping agent to synthesize silver nanowires through a polyol process.
Abstract
Polyvinyl pyrrolidone (PVP) with different molecular weights was used as capping agent to synthesize silver nanowires through a polyol process. The results indicated that the yields and aspect ratios of silver nanowires were controlled by the chain length of PVP and increased with increasing the molecular weight (MW) of PVP. When the long-chain PVP-K90 (MW= 800,000) was used, the product was uniform in size and was dominated by nanowires with high aspect ratios. The growth mechanism of the nanowires was studied. It is proposed that the chemical adsorption of Ag+ on the PVP chains at the initial stage promotes the growth of Ag nanowires.

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Recent advances in polymeric drug delivery systems

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Facile Synthesis of Sub-20 nm Silver Nanowires through a Bromide-Mediated Polyol Method

TL;DR: A simple and robust approach to the synthesis of Ag nanowires with diameters below 20 nm and aspect ratios over 1000 using a one-pot polyol method, which showed great mechanical flexibility and could be bent with acute angles without breaking.
References
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Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies

TL;DR: In this paper, the authors introduce the fundamentals of TEM and its applications in structural determination of shape-controlled nanocrystals and their assemblies, and demonstrate in situ TEM for characterizing and measuring the thermodynamic, electric, and mechanical properties of individual nanostructures, from which the structure−property relationship can be registered with a specific nanoparticle/structure.
Journal ArticleDOI

Plasmonics—A Route to Nanoscale Optical Devices

TL;DR: In this paper, a point dipole analysis predicts group velocities of energy transport that exceed 0.1c along straight arrays and shows that energy transmission and switching through chain networks such as corners and tee structures is possible at high efficiencies.
Journal ArticleDOI

Controlling anisotropic nanoparticle growth through plasmon excitation

TL;DR: It is demonstrated that the previously described photoinduced method for converting silver nanospheres into triangular silver nanocrystals—so-called nanoprisms—can be extended to synthesize relatively monodisperse nanoprism with desired edge lengths in the 30–120 nm range.
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