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Influence of ammonium polyphosphate-/poly(acrylic acid)-based layer by layer architectures on the char formation in cotton, polyester and their blends

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TLDR
In this paper, a complex, four-layered (or quadlayered) hybrid organic-inorganic architecture exploiting the Layer by Layer assembly is proposed to promote the formation of an aromatic and stable carbonaceous structure (char), able to thermally protect cotton, polyester and their blends.
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This article is published in Polymer Degradation and Stability.The article was published on 2012-09-01. It has received 84 citations till now. The article focuses on the topics: Ammonium polyphosphate & Acrylic acid.

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Journal ArticleDOI

Intumescence: Tradition versus novelty. A comprehensive review

TL;DR: The main concepts of intumescence are reviewed in this article, highlighting the novelties as well as the most significant results achieved in the flame retardancy of polymeric materials in the last 10-15 years.
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The contribution of washing processes of synthetic clothes to microplastic pollution.

TL;DR: Wash trials at real scale were performed on commercial clothes by using a household washing machine in order to gain reliable data about the release of microplastics, and to identify possible influences of textile characteristics on the release.
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Phosphorylated Cellulose Nanofibrils : A Renewable Nanomaterial for the Preparation of Intrinsically Flame-Retardant Materials

TL;DR: The nanopaper sheets prepared from phosphorylated CNF showed self-extinguishing properties after consecutive applications of a methane flame for 3 s and did not ignite under a heat flux of 35 kW/m2, as shown by flammability and cone calorimetry measurements, respectively.
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Flame-retardant surface treatments

TL;DR: Flame retardants mitigate the threat of fire from inherently flammable materials responsible for sustaining a high standard of living as mentioned in this paper, and there is now increased interest in the use of surface treatments to localize flame-retardant chemistry at the exterior of a material, where combustion occurs, in an effort to preserve desirable bulk properties and minimize the amount of additive needed.
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Flame retardant coatings prepared using layer by layer assembly: A review

TL;DR: In this paper, a review summarizes the research progress and future development trends of flame retardant coatings, including intumescent, non-intumescent and multifunctional coatings prepared using layer by layer assembly.
References
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Journal ArticleDOI

Flame retardant challenges for textiles and fibres: New chemistry versus innovatory solutions

TL;DR: In this article, a review of the development of the chemistry underlying most of today's successful and durable flame retardant treatments for fibres and textiles for cellulosic textiles is presented.
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Flame-Retardant Treatments of Cellulose and Their Influence on the Mechanism of Cellulose Pyrolysis

TL;DR: In this article, the problem of fire can be described as two distinct phenomena, glowing and flaming, which present different potential hazards and should be ap-proached in different ways Glowing is a direct oxidation of solid cellulose or its degradation products It is generally a slow combustion and is of great concern for only specific items, such as c
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Layer-by-layer assembly of silica-based flame retardant thin film on PET fabric

TL;DR: In this paper, PET fabrics were coated with colloidal silica nanoparticles using layer-by-layer assembly, and five bilayers of positively and negatively charged colloidal particles were used to improve flame retardant properties of textile fabric.
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Study of the mechanism of intumescence in fire retardant polymers. Part V: Mechanism of formation of gaseous products in the thermal degradation of ammonium polyphosphate

TL;DR: On heating, ammonium polyphosphate eliminates ammonia and water in two successive steps as mentioned in this paper, and the final product of degradation is characterised by a crosslinked P-O-P structure formed by elimination of H2O between P-O groups freed by the evolution of NH3.
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Layer by Layer ammonium polyphosphate-based coatings for flame retardancy of polyester–cotton blends

TL;DR: In this article, two different counterparts, i.e., chitosan molecules and silica nanoparticles, have been coupled with ammonium polyphosphate (APP)-based coatings in order to enhance the thermal stability in air and the flame retardancy properties of polyester-cotton blends.
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