Journal ArticleDOI
Interaction of vanadate with monosaccharides and nucleosides: a multinuclear NMR study.
TLDR
Proton, 13C and 51V nuclear magnetic resonance spectroscopy has been used to study the interaction of vanadate with several molecules containing more than one hydroxyl group, including various aldoses and nucleosides.About:
This article is published in Journal of Inorganic Biochemistry.The article was published on 1989-02-01. It has received 39 citations till now. The article focuses on the topics: Vanadate & Pyranose.read more
Citations
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Journal ArticleDOI
The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds.
TL;DR: Aqueous V(III) Chemistry 877 6.2.1.
Journal ArticleDOI
Carbohydrates as ligands: coordination equilibria and structure of the metal complexes
Béla Gyurcsik,László Nagy +1 more
TL;DR: A review of the literature on the metal ion complexes of carbohydrate type ligands with the emphasis on the past 20 years, discussing the equilibria and structure in aqueous solution together with the structures determined for the solid state complexes are collected for comparison as discussed by the authors.
Journal ArticleDOI
Metal coordination to carbohydrates. Structures and function
TL;DR: In this article, the role of the metal in complexing carbohydrate derivatives is discussed and the applications of such derivatives in biotechnology, agriculture, and pharmaceuticals are discussed. But the main focus is on bio-medical applications.
Journal ArticleDOI
Vanadium ionic species from degradation of Ti-6Al-4V metallic implants: In vitro cytotoxicity and speciation evaluation.
Bruna Carolina Costa,Cintia Kazuko Tokuhara,Luís Augusto Rocha,Rodrigo Cardoso de Oliveira,Paulo Noronha Lisboa-Filho,João Costa Pessoa +5 more
TL;DR: Even though relatively low concentrations of vanadium may be released from Ti-6Al-4V implants in vivo, the continuous contact with peri-implant cells for long periods of time may represent a potentially hazardous situation.
References
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Journal ArticleDOI
Effect of vanadate on elevated blood glucose and depressed cardiac performance of diabetic rats
TL;DR: Cardiac performance was depressed in the untreated diabetic animals, but the cardiac performance of the vanadate-treated diabetic animals was not significantly different from that of nondiabetic controls, so vanadates controlled the high blood glucose and prevented the decline in cardiac performance due to diabetes.
Journal ArticleDOI
The Composition and Conformation of Sugars in Solution
TL;DR: In this paper, the conformations of the aldoses in solution and the compositions of the equilibrium mixtures formed from aldosing after dissolution in water, have been determined by NMR spectroscopy.
Journal ArticleDOI
The proton magnetic resonance spectra and tautomeric equilibria of aldoses in deuterium oxide
R. U. Lemieux,J. D. Stevens +1 more
TL;DR: The proton magnetic resonance spectra of D-xylose, D-lyxose and D-arabinose were determined at 100 Mcp.s. in deuterium oxide as discussed by the authors.
Book ChapterDOI
The biochemistry of vanadium
TL;DR: There is ample evidence that vanadium in the body exists primarily as the vanadyl(IV) ion, VO2+, complexed to proteins and other cellular components; several biological reducing agents can convert vanadium(V) to this form.
Journal ArticleDOI
Studies on borate esters II
TL;DR: In this article, the pH dependent stability of boric acid and borate with glycol, glycolic acid, oxalic acid and glyceric acid as dihydroxy compounds has been studied.