Journal ArticleDOI
Interpenetrating metal–organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database
TLDR
In this article, a list of interpenetrating metal-organic 3D structures from CSD is presented, which are analyzed on the basis of their topologies and interesting trends and novel features have been observed.Abstract:
The occurrence of interpenetration in metal–organic and inorganic networks has been investigated by a systematic analysis of the CSD and ICSD structural databases. For this purpose, a novel version of TOPOS (a program package for multipurpose crystallochemical analysis) has been employed, where the procedure of recognition of interpenetrating nets is based on the representation of a crystal structure as a finite reduced graph. In this paper we report a comprehensive list (301 Refcodes) of interpenetrating metal–organic 3D structures from CSD, that are analyzed on the basis of their topologies. Interesting trends and novel features have been observed and distinct classes of interpenetrating nets have been envisaged, depending on the relationships of the individual motifs.read more
Citations
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Journal ArticleDOI
Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
Vladislav A. Blatov,Vladislav A. Blatov,A. P. Shevchenko,Davide M. Proserpio,Davide M. Proserpio +4 more
TL;DR: ToposPro as mentioned in this paper is a topological analysis of crystal structures realized in the current version of the program package ToposPro, which can be used to analyze various classes of chemical compounds including coordination polymers, molecular crystals, supramolecular ensembles, inorganic ionic compounds, intermetallics, fast-ion conductors, microporous materials.
Journal ArticleDOI
Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
Anh Phan,Christian J. Doonan,Fernando J. Uribe-Romo,Carolyn B. Knobler,Michael O'Keeffe,Omar M. Yaghi +5 more
TL;DR: The general preparation of crystalline ZIFs is described, discussing the methods that have been developed to create and analyze the variety of materials afforded and how complexity might be introduced into new structures.
Journal ArticleDOI
Zr-based metal-organic frameworks: design, synthesis, structure, and applications.
TL;DR: Advances in Zr-MOFs since 2008 are summarized and reviewed from three aspects: design and synthesis, structure, and applications to provide guidance for the in-depth investigation of MOFs towards practical applications.
Journal ArticleDOI
Tuning the structure and function of metal–organic frameworks via linker design
Weigang Lu,Zhangwen Wei,Zhi-Yuan Gu,Tian-Fu Liu,Jinhee Park,Jihye Park,Jian Tian,Muwei Zhang,Qiang Zhang,Thomas Gentle,Mathieu Bosch,Hong-Cai Zhou +11 more
TL;DR: This critical review of metal-organic frameworks (MOFs) highlights advances in MOF synthesis focusing on linker design and examples of building MOFs to reach unique properties, such as unprecedented surface area, pore aperture, molecular recognition, stability, and catalysis, through linkers are described.
Journal ArticleDOI
A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
Fernando J. Uribe-Romo,Joseph R. Hunt,Hiroyasu Furukawa,Cornelius Klöck,Michael O'Keeffe,Omar M. Yaghi +5 more
TL;DR: A new crystalline porous three-dimensional covalent organic framework, termed COF-300, has been synthesized and structurally characterized and shows thermal stability up to 490 degrees C and permanent porosity with a surface area of 1360 m(2) g(-1).
References
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Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Interpenetrating Nets: Ordered, Periodic Entanglement.
TL;DR: A detailed and systematic examination of many interpenetrating nets of this kind is made, and implications for crystal engineering are discussed.
Journal ArticleDOI
Polycatenation, polythreading and polyknotting in coordination network chemistry
TL;DR: The use of crystal engineering concepts has produced a variety of coordination networks, many of which exhibit novel and fascinating types of entanglements of individual motifs as mentioned in this paper, and the structures of a number of entangled polymeric networks reported in these years by many groups.