Iron Porphyrin Catalyzed N−H Insertion Reactions with Ethyl Diazoacetate
TLDR
In this article, a series of metalloporphyrin complexes were surveyed as catalysts for carbene insertion from ethyl diazoacetate into the N−H bonds of amines.About:
This article is published in Organometallics.The article was published on 2007-07-04 and is currently open access. It has received 98 citations till now. The article focuses on the topics: Ethyl diazoacetate & Insertion reaction.read more
Citations
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Iron-catalysed Carbene-Transfer Reactions of Diazo Acetonitrile
TL;DR: A continuous-flow protocol for the synthesis of diazo acetonitrile was developed and it was further applied in iron-catalysed insertion reactions of diazonitrile into N-H and S-H bonds to yield valuable α-substituted aconetitrile, including gram-scale synthesis.
Journal ArticleDOI
Metal-free C-C, C-O, C-S and C-N bond formation enabled by SBA-15 supported TFMSA
Xiangyan Yi,Xiangyan Yi,Jiangjun Feng,Jiangjun Feng,Fei Huang,Fei Huang,Jonathan B. Baell,Jonathan B. Baell +7 more
TL;DR: The construction of intermolecular C-C, C-O,C-S and C-N bonds between diazo compounds and acyclic and cyclic 1,3-dicarbonyl compounds, thiophenol and alkynes was developed using TFMSA@SBA-15, thus providing a metal-free and eco-friendly platform for forging those chemical bonds.
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Preparation of Axially Chiral 2,2′-Biimidazole Ligands through Remote Chirality Delivery and Their Application in Asymmetric Carbene Insertion into N–H of Carbazoles
TL;DR: These ligands have been proven to be efficient for Cu- or Fe-catalyzed asymmetric insertion of α-aryl-α-diazoacetates into the N-H bond of carbazoles with up to 96% ee.
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Phosphine ligands stabilized Cu(I) catalysts for carbene insertion into the N–H bond
TL;DR: In this paper, the authors used three different phosphine stabilized Cu(I) complexes (1, 3) as catalysts for chemoselective carbene insertion into the N-H bond of different aromatic amines over the formation of olefin (carbene dimerized product).
References
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Catalytic asymmetric epoxidations with chiral iron porphyrins
John T. Groves,Richard S. Myers +1 more
TL;DR: Epoxydation asymetrique d'olefines prochirales par des porphyrines de fer chirales and par des composes iodosyles.
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Spectra of the Metallo-derivatives of α,β,γ,δ-Tetraphenylporphine
Journal ArticleDOI
Catalytic Asymmetric C−H Activation of Alkanes and Tetrahydrofuran
TL;DR: Rhodium carbenoids derived from methyl aryldiazoacetates are capable of effective catalytic asymmetric C−H activation of a range of alkanes and tetrahydrofuran by a c−H insertion mechanism as mentioned in this paper.
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Copper(I) catalysis in cyclopropanations with diazo compounds. Role of olefin coordination
Robert G. Salomon,Jay K. Kochi +1 more
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The missing heme spin state and a model for cytochrome c'. The mixed S = 3/2, 5/2 intermediate spin ferric porphyrin: perchlorato(meso-tetraphenylporphinato)iron(III)
Christopher A. Reed,Toshio Mashiko,Steven P. Bentley,Margaret E. Kastner,W. Robert Scheidt,K. Spartalian,George Lang +6 more