Iron Porphyrin Catalyzed N−H Insertion Reactions with Ethyl Diazoacetate
TLDR
In this article, a series of metalloporphyrin complexes were surveyed as catalysts for carbene insertion from ethyl diazoacetate into the N−H bonds of amines.About:
This article is published in Organometallics.The article was published on 2007-07-04 and is currently open access. It has received 98 citations till now. The article focuses on the topics: Ethyl diazoacetate & Insertion reaction.read more
Citations
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Iron Porphyrin Carbenes as Catalytic Intermediates: Structures, Mössbauer and NMR Spectroscopic Properties, and Bonding
TL;DR: The first quantum chemical investigation of IPC Mössbauer and NMR spectroscopic properties, as well as their electronic structures, together with comparisons to ferrous heme proteins and an Fe(IV) oxene model are reported.
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DNA-Accelerated Catalysis of Carbene-Transfer Reactions by a DNA/Cationic Iron Porphyrin Hybrid
TL;DR: It is proposed that high effective molarity of all components of the reaction in or near the DNA is one of the key contributors to this unique reactivity.
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Thermally induced cycloadditions of donor/acceptor carbenes.
TL;DR: The thermal decomposition of aryldiazoacetates and aryLDiazoketones in the absence of a catalyst leads to synthetically useful transformations and good diastereocontrol.
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Metal-free N-H insertions of donor/acceptor carbenes.
TL;DR: Thermally generated, free donor/acceptor carbenes directly undergo N-H insertion with amines through selective aza-ylide formation to afford a variety of α-amino esters in 53-96% yields.
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Chemoselective Cyclopropanation over Carbene Y–H Insertion Catalyzed by an Engineered Carbene Transferase
TL;DR: The development of a novel artificial metalloenzyme based on an engineered myoglobin incorporating a serine-ligated Co-porphyrin cofactor that is capable of offering high selectivity toward olefin cyclopropanation over N-H and Si-H insertion is described.
References
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Journal ArticleDOI
Catalytic asymmetric epoxidations with chiral iron porphyrins
John T. Groves,Richard S. Myers +1 more
TL;DR: Epoxydation asymetrique d'olefines prochirales par des porphyrines de fer chirales and par des composes iodosyles.
Journal ArticleDOI
Spectra of the Metallo-derivatives of α,β,γ,δ-Tetraphenylporphine
Journal ArticleDOI
Catalytic Asymmetric C−H Activation of Alkanes and Tetrahydrofuran
TL;DR: Rhodium carbenoids derived from methyl aryldiazoacetates are capable of effective catalytic asymmetric C−H activation of a range of alkanes and tetrahydrofuran by a c−H insertion mechanism as mentioned in this paper.
Journal ArticleDOI
Copper(I) catalysis in cyclopropanations with diazo compounds. Role of olefin coordination
Robert G. Salomon,Jay K. Kochi +1 more
Journal ArticleDOI
The missing heme spin state and a model for cytochrome c'. The mixed S = 3/2, 5/2 intermediate spin ferric porphyrin: perchlorato(meso-tetraphenylporphinato)iron(III)
Christopher A. Reed,Toshio Mashiko,Steven P. Bentley,Margaret E. Kastner,W. Robert Scheidt,K. Spartalian,George Lang +6 more