Magnetic Ionic Liquids in Sample Preparation: Recent Advances and Future Trends
Theodoros Chatzimitakos,Phoebe Anagnostou,Ioanna Constantinou,Kalliroi Dakidi,Constantine D. Stalikas +4 more
TLDR
The use of magnetic ionic liquids (MILs) as non-conventional solvents for sample preparation has been studied in the literature as mentioned in this paper, where the authors provide a literature update on the current trends of MILs in different modes of sample preparation, along with the current limitations and the prospects of the field.Abstract:
In the last decades, a myriad of materials has been synthesized and utilized for the development of sample preparation procedures. The use of their magnetic analogues has gained significant attention and many procedures have been developed using magnetic materials. In this context, the benefits of a new class of magnetic ionic liquids (MILs), as non-conventional solvents, have been reaped in sample preparation procedures. MILs combine the advantageous properties of ionic liquids along with the magnetic properties, creating an unsurpassed combination. Owing to their unique nature and inherent benefits, the number of published reports on sample preparation with MILs is increasing. This fact, along with the many different types of extraction procedures that are developed, suggests that this is a promising field of research. Advances in the field are achieved both by developing new MILs with better properties (showing either stronger response to external magnetic fields or tunable extractive properties) and by developing and/or combining methods, resulting in advanced ones. In this advancing field of research, a good understanding of the existing literature is needed. This review aims to provide a literature update on the current trends of MILs in different modes of sample preparation, along with the current limitations and the prospects of the field. The use of MILs in dispersive liquid–liquid microextraction, single drop microextraction, matrix solid-phase dispersion, etc., is discussed herein among others.read more
Citations
More filters
Journal ArticleDOI
Optimization of magnetic ionic based dispersive liquid-liquid microextraction of cadmium in water and food samples using experimental design prior to flame atomic absorption spectrophotometry
Adil Elik,Nail Altunay +1 more
TL;DR: A magnetic ionic based dispersive liquid liquid microextraction (MIL-DLLME) procedure was optimized for the analysis and extraction of cadmium in water and food samples by flame atomic absorption spectrophotometry (FAAS) as discussed by the authors .
Journal ArticleDOI
Magnetic Ionic Liquids in Analytical Microextraction: A Tutorial Review.
TL;DR: Magnetic ionic liquids (MILs) are materials of special interest in analytical chemistry and particularly in analytical microextraction as discussed by the authors , and they possess several of the properties derived from their inherent nature of ionic liquid, combined with their magnetism, that permits their manipulation with an external magnetic field.
Journal ArticleDOI
Experimental and Computational Study of the Properties of Imidazole Compounds with Branched and Cycloalkyl Substituents
TL;DR: In this article , a linear and parabolic model was used for temperature-density correlation while temperature dependence of viscosity was summarized using the Andrade Equation and the Vogel-Fulcher-Tammann equation.
Journal ArticleDOI
Assessment of the Equilibrium Constants of Mixed Complexes of Rare Earth Elements with Acidic (Chelating) and Organophosphorus Ligands
TL;DR: A survey of the experimental equilibrium constants in solution for the mixed complexes of 4f ions with acidic (chelating) and O-donor organophosphorus ligands published in the period between 1954 and 2022 is presented in this paper .
Journal ArticleDOI
Development and Application of Green or Sustainable Strategies in Analytical Chemistry
TL;DR: In this article , the authors present growing challenges in the near future, especially for the quantification of trace analytes in complex matrices, for the purpose of trace analysis in analytical chemistry.
References
More filters
Journal ArticleDOI
Advances in Solid Phase Microextraction and Perspective on Future Directions.
Nathaly Reyes-Garcés,Emanuela Gionfriddo,Germán Augusto Gómez-Ríos,Md. Nazmul Alam,Ezel Boyacı,Barbara Bojko,Varoon Singh,Jonathan J. Grandy,Janusz Pawliszyn +8 more
TL;DR: A growing number of reports describing diverse SPME workflows for novel investigations in a variety of fields, such as flavor and fragrance investigations, environmental studies, and diverse bioanalytical applications, corroborate the applicability of this microextraction tool in the analytical sciences.
Journal ArticleDOI
Measuring anxiety in zebrafish: a critical review.
Caio Maximino,Thiago Marques de Brito,Annanda Waneza da Silva Batista,Anderson Manoel Herculano,Silvio Morato,Amauri Gouveia +5 more
TL;DR: Some notions of validity are reviewed, arguing that, at its limit, face and predictive validity reduce to construct validity, and it is concluded that there is still a long way to go in reaching the desired level of construct validity.
Journal ArticleDOI
Application of carbon-based nanomaterials in sample preparation: a review.
TL;DR: A broad overview on the applications of different carbon-based nanomaterials, including nanodiamonds, fullerenes, carbon nanotubes, graphene,carbon nanofibers, carbon Nanocones-disks and nanohorns, as well as their functionalized forms, in sample preparation is provided.
Journal ArticleDOI
Determination of pesticide residues in olives and olive oil by matrix solid-phase dispersion followed by gas chromatography/mass spectrometry and liquid chromatography/tandem mass spectrometry
Carmen María Salvador Ferrer,M. José Gómez,Juan F. García-Reyes,Imma Ferrer,E. Michael Thurman,Amadeo R. Fernández-Alba +5 more
TL;DR: The recoveries obtained, confirm the usefulness of the proposed methodology for the analyses of these kind of complex samples with a high fat content, and the obtained detection limits meet the requirements established by the olive oil pesticide regulatory programs.
Journal ArticleDOI
Highly efficient extraction of phenolic compounds by use of magnetic room temperature ionic liquids for environmental remediation
TL;DR: A hydrophobic magnetic room temperature ionic liquid (MRTIL) synthesized from trihexyltetradecylphosphonium chloride and FeCl(3) · 6H(2)O was investigated as a possible separation agent for solvent extraction of phenolic compounds from aqueous solution and found to have higher distribution ratios under acidic conditions.