Journal ArticleDOI
MCM-41 supported water-soluble TPPTS-Rh complex in ionic liquids: A new robust catalyst for olefin hydroformylation
TLDR
MCM-41 mesoporous silicas-supported water-soluble TPPTS-Rh complex in the ionic liquid TMGL exhibited high performance and stability for the hydroformylation of 1-hexene, and the catalyst system co...Abstract:
MCM-41 mesoporous silicas-supported water-soluble TPPTS–Rh complex in the ionic liquid TMGL exhibited high performance and stability for the hydroformylation of 1-hexene, and the catalyst system co...read more
Citations
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Journal ArticleDOI
Catalysis in ionic liquids
TL;DR: Hydrogenation of Alkenes and Arenes by Nanoparticles 2624 3.1.2.
Journal ArticleDOI
Preparation of Inorganic Materials Using Ionic Liquids
Zhen Ma,Jihong Yu,Sheng Dai +2 more
TL;DR: In this Review, the use of ionic liquids in the preparation of several categories of inorganic and hybrid materials (i.e., metal structures, non-metal elements, silicas, organosilicas, metal oxides, metal chalcogenide, metal salts, open-framework structures, ionic liquid-functionalized materials, and supported ionsic liquids) is summarized.
Journal ArticleDOI
Supported Ionic Liquid Phase (SILP) Catalysis: An Innovative Concept for Homogeneous Catalysis in Continuous Fixed-Bed Reactors
TL;DR: In this article, the authors present results for the continuous gas-phase hydroformylation of propene, as a reaction example, using a supported ionic liquid phase (SILP) approach.
Journal ArticleDOI
Supported ionic liquids: versatile reaction and separation media
TL;DR: The latest developments in supported ionic liquid phase (SILP) systems for catalysis and separation technology are surveyed in this article, where a variety of reactions have been studied where SILP catalysts proved to be more active and selective than common systems.
Journal ArticleDOI
Hydroformylation in room temperature ionic liquids (RTILs): catalyst and process developments.
Marco Haumann,Anders Riisager +1 more
TL;DR: Over the last few years, ionic liquids have successfully been applied as alternative solvents for homogeneous biphasic catalysis, and an important advantage is the possibility to tune their solubility and acidity/coordination properties by varying the nature of the anions and cations systematically.
References
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Journal ArticleDOI
Ionic Liquids-New "Solutions" for Transition Metal Catalysis.
Peter Wasserscheid,Wilhelm Keim +1 more
TL;DR: There are indications that switching from a normal organic solvent to an ionic liquid can lead to novel and unusual chemical reactivity, which opens up a wide field for future investigations into this new class of solvents in catalytic applications.
Journal ArticleDOI
Ionic liquid (molten salt) phase organometallic catalysis.
TL;DR: The advent of water-soluble organometallic complexes, especially those based on sulfonated phosphorus-containing ligands, has enabled various biphasic catalytic reactions to be conducted on an industrial scale and might combine the advantages of both homogeneous and heterogeneous catalysis.
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Supported ionic liquid catalysis--a new concept for homogeneous hydroformylation catalysis.
TL;DR: The new concept of supported ionic liquid catalysis involves the surface of a support material that is modified with a monolayer of covalently attached ionicLiquid fragments that serves as the reaction phase in which a homogeneous hydroformylation catalyst was dissolved.
Journal ArticleDOI
A Novel Class of Versatile Solvents for Two-Phase Catalysis: Hydrogenation, Isomerization, and Hydroformylation of Alkenes Catalyzed by Rhodium Complexes in Liquid 1,3-Dialkylimidazolium Salts
Journal ArticleDOI
Immobilised Ionic Liquids as Lewis Acid Catalysts for the Alkylation of Aromatic Compounds with Dodecene
TL;DR: In this article, inert ionic liquids were used as acid catalysts for the alkylation of benzene, toluene, naphthalene, and phenol with dodecene.