Journal ArticleDOI
Mechanisms and kinetics of thermal reactions of aromatic hydrocarbons from pyrolysis of solid fuels
TLDR
In this article, the kinetics of the thermal conversion of aromatic hydrocarbons in the presence of hydrogen and steam were studied, using anphthalene, toluene and benzene as model compounds.About:
This article is published in Fuel.The article was published on 1996-10-01. It has received 372 citations till now. The article focuses on the topics: Benzene & Hydrogen.read more
Citations
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ReportDOI
Biomass Gasifier "Tars": Their Nature, Formation, and Conversion
TL;DR: In this article, the authors present the scientific and practical aspects of tar formation and conversion during gasification as a function of various technological and technical parameters and variables, and present a review of the most cumbersome and problematic parameter in any gasification commercialization effort.
Journal ArticleDOI
An overview of advances in biomass gasification
Vineet Singh Sikarwar,Ming Zhao,Ming Zhao,Peter T. Clough,Joseph G. Yao,Xia Zhong,Mohammad Zaki Memon,Nilay Shah,Edward J. Anthony,Paul S. Fennell +9 more
TL;DR: In this paper, an assessment on the fundamentals such as feedstock types, the impact of different operating parameters, tar formation and cracking, and modelling approaches for biomass gasification is presented.
Journal ArticleDOI
Tar property, analysis, reforming mechanism and model for biomass gasification—An overview
Chunshan Li,Kenzi Suzuki +1 more
TL;DR: In this article, a detailed overview on tar chemical and physical properties, reforming mechanism and reaction kinetic model are summarized in a detail overview on coal-to-tar conversion process is presented.
Journal ArticleDOI
Biomass gasification technology: The state of the art overview
TL;DR: In this article, the state of the art biomass gasification technologies, evaluating advantages and disadvantages, the potential use of the syngas and the application of the biomass, are presented.
Journal ArticleDOI
Mechanisms and kinetics of homogeneous secondary reactions of tar from continuous pyrolysis of wood chips
TL;DR: In this article, the change of mass and composition of biomass tar due to homogeneous secondary reactions was experimentally studied by means of a lab reactor system that allows the spatially separated production and conversion of the biomass tar.
References
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Journal ArticleDOI
Evaluated Kinetic Data for Combustion Modelling
Donald L. Baulch,Carlos J. Cobos,Richard A. Cox,C. Esser,P. Frank,Th. Just,J. A. Kerr,Michael J. Pilling,Jürgen Troe,Raymond W. Walker,J. Warnatz +10 more
TL;DR: In this paper, the authors present a compilation of critically evaluated kinetic data on elementary homogeneous gas phase chemical reactions for use in modelling combustion processes Data sheets are presented for some 196 reactions each data sheet sets out relevant thermodynamic data, rate coefficient measurements, an assessment of the reliability of the data, references and recommended rate parameters Tables summarizing the preferred rate data are also given
Journal ArticleDOI
The C–H Bond Energy in Toluene and Xylenes
TL;DR: In this article, the pyrolysis of toluene and the xylenes was investigated by a new technique, which made it possible to study these reactions for degree of decomposition ranging from 0.01 percent up to a few percent.
Journal ArticleDOI
Steam gasification of naphthalene as a model reaction of homogeneous gas/gas reactions during coal gasification
Ximena García,Klaus J. Hüttinger +1 more
TL;DR: In this paper, the naphthalene-steam reaction was studied as a model reaction for homogeneous gas/gas reactions in coal gasification, and the experiments were performed in an isothermal flow tube reactor.
Journal ArticleDOI
Chemistry of methane formation in hydrogasification of aromatics. 1. Non-substituted aromatics
TL;DR: In this paper, the chemistry of the formation of methane in hydrogasification of such unsubstituted aromatics as benzene, naphthalene, phenanthrene, anthracene and biphenyl was studied using a flow tube.
Reaktionskinetische Untersuchungen zur thermischen Zersetzung von Modellkohlenwasserstoffen
TL;DR: In this paper, the authors present the results of a study of thermal decomposition of model hydrocarbons based on the concept of a two-product coking plant, which works without the common but expensive cleaning of the raw coke-oven gas.