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Journal ArticleDOI

Mesoporous Tyrosine Functionalized BTC-ZnO Composite for Highly Selective Capacitive CO Sensor

TLDR
In this paper, the performance of the mesoporous structures in room temperature gas sensing was studied for the CO concentration range of 5-300 ppm in synthetic air, and the improvement in the capacitance change, quicker response time, good linearity and reversibility was attributed to the synergistic effect between ZnO and tyrosine functionalized BTC.
Abstract
Drop-casting is a simple deposition technique where a slurry-like solution of nanomaterial is coated on small substrates, which are then allowed to dry under controlled temperature and pressure ambience. The present work focuses on the tyrosine functionalized benzene-tri-carboxyamide (Tyr-BTC) and ZnO composite based sensor deposited using drop-cast method for sensing carbon monoxide (CO) at room temperature. The composition of the composite surface was varied by altering the molar concentration of the constituents. The performance of the mesoporous structures in room temperature gas sensing was studied for the CO concentration range of 5–300 ppm in synthetic air. The highly amplified gas sensing response of approximately 94% at 300 ppm of CO by Tyr-BTC-ZnO in molar concentration 2:3 of Tyr-BTC-ZnO was observed. The improvement in the capacitance change, quicker response time, good linearity and reversibility was attributed to the synergistic effect between ZnO and tyrosine functionalized BTC.

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Citations
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Journal ArticleDOI

Photocatalytic Behaviour of Zinc Oxide Nanostructures on Surface Activation of Polymeric Fibres.

TL;DR: In this paper, the role of photocatalytic activity (role of photogenerated radical scavengers) of nano ZnO (nZnO) for surface activation of polymeric natural fibres especially cotton and their combined effect in photocatalysis applications is investigated.
Journal Article

Organo-di-benzoic-acidified ZnO Nanohybrids for Highly Selective Detection of CO at Low Temperature

TL;DR: In this paper, a chemiresistive carbon monoxide (CO) gas sensor comprising of an organo-di-benzoic acidified zinc oxide (ODBA-ZnO) nanohybrid material is reported.
Journal ArticleDOI

DFT based Comparative Study of Pristine gCN and gCN-ZnO Composite as a Sensor for CO and CO2Gases

TL;DR: In this paper , the sensing behavior of pristine gCN and gCN-ZnO composite towards CO and CO2 gases has been analyzed using DFT, and the results revealed that the sensing performance of gCN is enhanced by incorporating ZnO.
Journal ArticleDOI

Green nanocomposite: fabrication, characterization, and photocatalytic application of vitamin C adduct-conjugated ZnO nanoparticles

TL;DR: In this article , a green and biodegradable vitamin C was employed in a facile and inexpensive procedure to synthesize the vitamin C adduct (3), which was then blended with green ZnONPs to fabricate a new composite category (ZnONP@vitaminC adduct), and the morphology and structural composition of the prepared ZnNPs and their composites were confirmed by several techniques: Fourier-transform infrared (FT-IR) spectroscopy, field-emission scanning electron microscopy (FE-SEM), UV-vis differential reflectance spectrograph (DRS), energy dispersive X-ray (EDX) analysis, elemental mapping, XRD analysis, photoluminescence (PL) spectrograms, and zeta potential measurements.
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Photocatalytic activity of ZnO under near-real conditions

TL;DR: In this article , the photocatalytic activity of ZnO decreases twice after four cycles of use without regeneration and remains equally high after complete regeneration, and the best results were obtained at the zinc oxide dose of 2.0 g per 2. 0 g of dye.
References
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Journal ArticleDOI

Fabrication of green and orange photoluminescent, undoped ZnO films using spray pyrolysis

TL;DR: In this paper, photoluminescent, undoped ZnO films have been fabricated using spray pyrolysis of zinc nitrate solution using a polycrystalline hexagonal wurtzite type structure with no preferred orientation.
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Metal-organic frameworks with high capacity and selectivity for harmful gases

TL;DR: It is found that pore functionality plays a dominant role in determining the dynamic adsorption performance of MOFs, and MOFs featuring reactive functionality outperform BPL carbon in all but one case and exhibit high dynamic adsorbents capacities up to 35% by weight.
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Metal oxide nano-crystals for gas sensing.

TL;DR: The gas experiments presented confirm good sensing properties, the possibility to use dopants and catalyser such in thin film gas sensors and the real integration in low power consumption transducers of single crystalline nanobelts prove the feasibility of large scale manufacturing of well-organized sensor arrays based on different nanostructures.
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Gas sensors using carbon nanomaterials: A review

TL;DR: In this article, the state of the art for electrical gas sensors employing carbon nanomaterials, identifies the bottlenecks that impair their commercialisation and also some recent breakthroughs.
Journal ArticleDOI

Molecular Simulation of Carbon Dioxide/Methane/Hydrogen Mixture Adsorption in Metal−Organic Frameworks

TL;DR: This work performs a systematic computational study toward a molecular understanding of the separation characteristics of metal-organic frameworks (MOFs), for which the purification of synthetic gas by two representative MOFs, MOF-5 and Cu-BTC, is adopted as an example.
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