Journal ArticleDOI
Metal–organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)2(bipy)] and [Co2(mal)2(bipy)(H2O)2] (phth = phthalate, mal = malonate, bipy = 4,4′-bipyridine)†
Philip Lightfoot,Alan Snedden +1 more
TLDR
In this paper, two metal-organic co-ordination frameworks have been prepared hydrothermally in mixed ligand systems and their crystal structures determined: [Co(phth)2(bipy)] is composed of a complex three-dimensional framework consisting of interlinked Co-phth-Co and Co-biopyridine chains.Abstract:
Two new metal–organic co-ordination frameworks have been prepared hydrothermally in mixed ligand systems and their crystal structures determined: [Co(phth)2(bipy)] is composed of a complex three-dimensional framework consisting of interlinked Co–phth–Co and Co–bipy–Co chains; [Co2(mal)2(bipy)(H2O)2] is also three-dimensional, being composed of Co–mal sheets which are pillared by bidentate bipy molecules (phth = phthalate, mal = malonate, bipy = 4,4′-bipyridine). Both frameworks enclose small void channels.read more
Citations
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Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
TL;DR: In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.
Journal ArticleDOI
Coordination polymers and metal–organic frameworks based on poly(pyrazole)-containing ligands
TL;DR: In this article, a survey on transition metal containing coordination polymers and metal-organic frameworks (MOFs) with poly(pyrazole)-and poly (pyrazolate)-based ligands is presented, where up to three N-donor heterocyclic rings are organized on rigid or flexible cores.
Journal ArticleDOI
Magneto-structural xorrelations in 2D and 3D extended structures of manganese(II)-malonate systems.
Tapas Kumar Maji,Saugata Sain,Golam Mostafa,Tian-Huey Lu,Joan Ribas,Montserrat Monfort,Nirmalendu Ray Chaudhuri +6 more
TL;DR: Two polymeric malonato-bridged manganese(II) complexes of formula [Mn(mal)(H(2)O)(2)](n)() (2) have been synthesized and characterized and the structure determination reveals that the complex is a 3D network being composed of Mn-malonate sheets which are pillared by bidentate 4,4'-bipy spacer forming small voids.
Journal ArticleDOI
Hydrothermal Syntheses, Crystal Structures, and Properties of a Novel Class of 3,3‘,4,4‘-Benzophenone-tetracarboxylate (BPTC) Polymers
TL;DR: Three novel BPTC complexes were hydrothermally synthesized and the photoluminescence properties of complexes 1-2 and temperature-dependent magnetic susceptibility for 3 were studied.
References
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Completion and refinement of crystal structures with SIR92
TL;DR: In this paper, an automatic procedure for recovering a complete crystal structure after a direct phasing process is described, which consists mainly of a Fourier recycling method that can be implemented in any direct-methods package.
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Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid
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Functional Micropore Chemistry of Crystalline Metal Complex-Assembled Compounds
Susumu Kitagawa,Mitsuru Kondo +1 more
TL;DR: In this paper, a wide variety of micropore chemistry of metal complex-based assemblages is directed toward not only new frameworks but also functionalities such as gas and small molecule adsorption, ion exchange, heterogeneous catalysis, photo-chemical and physical properties.
Journal ArticleDOI
Functional Organic Analogues of Zeolites Based on Metal–Organic Coordination Frameworks
TL;DR: The current state of research on intercalation has concentrated largely on nanoporous inorganic materials such as aluminosilicates (zeo- lites), aluminophosphates, pillared clays, and graphite as discussed by the authors.