Journal ArticleDOI
Metal organic frameworks for sensing applications
TLDR
This review focuses on recent progress achieved in MOF research with respect to general sensing principles and analytical performance, and discusses future industrial applications in sensing that are of immense research interest.Abstract:
A metal organic framework (MOF) represents a new class of hybrid material built from metal ions with well-defined coordination geometry and organic bridging ligands Over the past few years, MOFs have attracted a great deal of attention due to their intriguing framework architecture, topology, and optical properties MOFs have provided promising perspectives in various research fields, such as catalysis, energy storage, drug-delivery systems, non-linear optics, and gas storage Recently, the application of MOFs was further extended to cover new, interesting fields of sensing toward various target components, including small molecules, solvents, pesticides, explosives, and biological markers In this review, we focus on recent progress achieved in MOF research with respect to general sensing principles and analytical performance This review also discusses future industrial applications in sensing that are of immense research interestread more
Citations
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Journal ArticleDOI
Metal–organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions
Jie Li,Jie Li,Xiangxue Wang,Guixia Zhao,Changlun Chen,Zhifang Chai,Ahmed Alsaedi,Tasawar Hayat,Xiangke Wang,Xiangke Wang,Xiangke Wang +10 more
TL;DR: This review focuses on recent progress in reported MOFs and MOF-based composites as superior adsorbents for the efficient removal of toxic and nuclear waste-related metal ions.
Journal ArticleDOI
Metal-Organic Frameworks for the Removal of Emerging Organic Contaminants in Water.
Sara Rojas,Patricia Horcajada +1 more
TL;DR: This review highlights the advances in the use of MOFs in the elimination (adsorption and/or degradation) of EOCs from water, classifying them by the nature of the contaminant.
Journal ArticleDOI
Metal–organic frameworks (MOFs) for the removal of emerging contaminants from aquatic environments
Sarita Dhaka,Sarita Dhaka,Rajesh Kumar,Rajesh Kumar,Akash Deep,Mayur B. Kurade,Sangwoo Ji,Byong-Hun Jeon +7 more
TL;DR: In this article, the performance of metal-organic frameworks (MOFs) for aqueous phase sorptive removal of emerging contaminants (ECs) from water has been evaluated.
Journal ArticleDOI
Functional Nanomaterials and Nanostructures Enhancing Electrochemical Biosensors and Lab-on-a-Chip Performances: Recent Progress, Applications, and Future Perspective.
TL;DR: This review answers many questions around the nanomaterials used, their inherent properties and the chemistries they offer that are of interest to the analytical systems, and their roles in analytical applications in the past 5 years (2013-2018), and it gives a quantitative assessment of their positive effects on the analyses.
Journal ArticleDOI
Recent advances in enzyme immobilization techniques: Metal-organic frameworks as novel substrates
Jyotsana Mehta,Jyotsana Mehta,Neha Bhardwaj,Neha Bhardwaj,Sanjeev K. Bhardwaj,Sanjeev K. Bhardwaj,Ki-Hyun Kim,Akash Deep,Akash Deep +8 more
TL;DR: In this article, the authors discuss different approaches used in the development of MOF-enzyme biocatalytic supports, such as surface adsorption, diffusion, and in-situ encapsulation.
References
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.