Journal ArticleDOI
Metallophthalocyanines as catalysts in electrochemical reactions
TLDR
The factor that controls the activity of these chelates is not fully understood but parameters such as redox potentials of the metal and electronic structure appear to be crucial as discussed by the authors.About:
This article is published in Coordination Chemistry Reviews.The article was published on 1992-10-15. It has received 499 citations till now.read more
Citations
More filters
Journal ArticleDOI
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
TL;DR: The emphasis of this review is on the origin of the electrocatalytic activity of nanostructured catalysts toward a series of key clean energy conversion reactions by correlating the apparent electrode performance with their intrinsic electrochemical properties.
Journal ArticleDOI
A review on non-precious metal electrocatalysts for PEM fuel cells
TL;DR: In this paper, the authors highlight the progress made over the past 40 years with a detailed discussion of recent works in the area of non-precious metal electrocatalysts for oxygen reduction reaction, a necessary reaction at the PEM fuel cell cathode.
Journal ArticleDOI
Understanding the High Activity of Fe-N-C Electrocatalysts in Oxygen Reduction: Fe/Fe3C Nanoparticles Boost the Activity of Fe-N(x).
Wen-Jie Jiang,Lin Gu,Li Li,Yun Zhang,Yun Zhang,Xing Zhang,Linjuan Zhang,Jianqiang Wang,Jin-Song Hu,Zidong Wei,Li-Jun Wan +10 more
TL;DR: A new highly active Fe-n-C ORR catalyst containing Fe-N(x) coordination sites and Fe/Fe3C nanocrystals (Fe@C-FeNC) is developed, and the origin of its activity is revealed by intensively investigating the composition and the structure of the catalyst and their correlations with the electrochemical performance.
Journal ArticleDOI
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
TL;DR: Ruthenium Complexes as a Source of Inspiration, Reduction of Carbon Dioxide, and Concluding Remarks.
Journal ArticleDOI
Phthalocyanines: old dyes, new materials. Putting color in nanotechnology
TL;DR: WhyPhthalocyanines are versatile building blocks for fabricating materials at the nanometer scale and are targets for different scientific purposes and technological applications is described.
References
More filters
Journal ArticleDOI
A New Fuel Cell Cathode Catalyst
TL;DR: The use of metal phthalocyanines as catalysts for the oxidation of organic compounds has been described in the literature as mentioned in this paper, and a number of these reports were tested as cathode catalysts in fuel cells.
Journal ArticleDOI
Spectra of porphyrins: Part II. Four orbital model
TL;DR: In this paper, the configuration interaction parameters for reduced porphyrins, azaporphins, and benzporphins were determined using the LCAO-MO (Huckel) calculation.
Journal ArticleDOI
Synthetic oxygen carriers related to biological systems
Journal ArticleDOI
Electrode catalysis of the four-electron reduction of oxygen to water by dicobalt face-to-face porphyrins
TL;DR: In this paper, a series of dimeric metalloporphyrin molecules has been synthesized in which the two porphrin rings are constrained to lie parallel to one another by two amide bridges of varying length that link the rings together.