Journal ArticleDOI
Micropolarity and aggregation behavior in ionic liquid + organic solvent solutions
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In this paper, the physicochemical and structural properties of binary or ternary mixtures of 1- n -butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF 6 ])+ organic solvent were studied.About:
This article is published in Fluid Phase Equilibria.The article was published on 2006-10-20. It has received 62 citations till now. The article focuses on the topics: Ionic liquid & Solvent.read more
Citations
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Journal ArticleDOI
Multiscale Studies on Ionic Liquids
TL;DR: The present review aims to summarize the recent advances in the fundamental and application understanding of ILs, and introduces the structures and properties of typical ILs.
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Conductivities of Binary Mixtures of Ionic Liquids with Polar Solvents
TL;DR: In this article, the conductivity of selected binary mixtures of the ionic liquids with polar solvents (water, propylene carbonate, dimethylsulfoxide, methanol, dichloromethane) at 25 °C were reported.
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Liquid–liquid extraction of actinides, lanthanides, and fission products by use of ionic liquids: from discovery to understanding
TL;DR: Liquid–liquid extraction of actinides and lanthanides by use of ionic liquids is reviewed, considering, first, phenomenological aspects, then looking more deeply at the various mechanisms.
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Imidazolium ionic liquids as additives of the synthetic ester propylene glycol dioleate in aluminium–steel lubrication
A.E. Jiménez,M.D. Bermúdez +1 more
TL;DR: In this article, four room-temperature ionic liquids (ILs), 1-C n H 2 n +1 -3-CH 3 -imidazolium X − [X=PF 6 ; n ǫ=6 (L-P106), X=BF 4 ; nǫ = 2 (L102), 6 (L106).
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Imidazolium Salt Ion Pairs in Solution
TL;DR: Electric conductivity, NMR, ESI-MS and IR data as well as theoretical calculations support not only the formation of contact ion pairs in solution, but also the presence of larger ionic and neutral aggregates even when dissolved in solvents with relatively high dielectric constants, such as acetonitrile and DMSO.
References
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Book
Lange's Handbook of Chemistry
TL;DR: This encyclopedic work includes authoritative coverage of atomic and molecular structure, organic chemistry (revised), inorganic, analytical, and electro- chemistry, mathematics as applied to chemistry, and more.
Journal ArticleDOI
Ionic Liquids-New "Solutions" for Transition Metal Catalysis.
Peter Wasserscheid,Wilhelm Keim +1 more
TL;DR: There are indications that switching from a normal organic solvent to an ionic liquid can lead to novel and unusual chemical reactivity, which opens up a wide field for future investigations into this new class of solvents in catalytic applications.
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Ionic Liquids--Solvents of the Future?
TL;DR: Rogers and Seddon as discussed by the authors reviewed recent progress on developing new ionic liquid solvents for use in chemical synthesis, catalysis, fuel cells, and other applications.
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Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
TL;DR: The first systematic study of the effect of impurities and additives (e.g., water, chloride, and cosolvents) on the physical properties of room-temperature ionic liquids was performed in this article.