Microstructural study of a nitroxide-mediated poly(ethylene oxide)/polystyrene block copolymer (PEO-b-PS) by electrospray tandem mass spectrometry
TLDR
Electrospray ionization tandem mass spectrometry has been used to characterize the microstructure of a nitroxide-mediated poly(ethylene oxide)/polystyrene block copolymer, called SG1-capped PEO-b-PS, suggesting that rearrangement reactions do not compete effectively with dissociations of the odd-electron fragment ions.About:
This article is published in Journal of the American Society for Mass Spectrometry.The article was published on 2008-08-01 and is currently open access. It has received 45 citations till now. The article focuses on the topics: Collision-induced dissociation & Fragmentation (mass spectrometry).read more
Citations
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Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries
Renaud Bouchet,Sébastien Maria,Rachid Meziane,Abdelmaula Aboulaich,Livie Liénafa,Jean-Pierre Bonnet,Trang N. T. Phan,Denis Bertin,Didier Gigmes,Didier Devaux,Renaud Denoyel,Michel Armand +11 more
TL;DR: A multifunctional single-ion polymer electrolyte based on polyanionic block copolymers comprising polystyrene segments overcomes most of the above limitations, with a lithium-ion transport number close to unity, excellent mechanical properties and an electrochemical stability window spanning 5 V versus Li(+)/Li.
Journal ArticleDOI
Review of lithium effects on brain and blood.
TL;DR: Lithium has been reported to be beneficial in animal models of brain injury, stroke, Alzheimer's, Huntington's, and Parkinson's diseases, amyotrophic lateral sclerosis (ALS), spinal cord injury, and other conditions.
Mass spectrometry in polymer chemistry: A state-of-the-art up-date
Till Gruendling,Till Gruendling,Steffen M. Weidner,Jana Falkenhagen,Christopher Barner-Kowollik +4 more
TL;DR: A review of the state-of-the-art soft ionization mass spectrometers can be found in this paper, covering the latest developments of novel techniques, enabling instrumentation as well as the important applications.
Journal ArticleDOI
Mass spectrometry in polymer chemistry: a state-of-the-art up-date
Till Gruendling,Till Gruendling,Steffen M. Weidner,Jana Falkenhagen,Christopher Barner-Kowollik +4 more
TL;DR: A review of the state-of-the-art soft ionization mass spectrometers can be found in this paper, covering the latest developments of novel techniques, enabling instrumentation as well as the important applications of soft ionisation MS from the beginning of 2008.
Journal ArticleDOI
Fragmentation pathways of polymer ions.
Chrys Wesdemiotis,Nilüfer Solak,Michael J. Polce,David E. Dabney,Kittisak Chaicharoen,Bryan C. Katzenmeyer +5 more
TL;DR: This article reviews the fragmentation pathways of synthetic polymer ions that have been energized to decompose via collisionally activated dissociation (CAD), the most widely used activation method in polymer analysis.
References
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Journal ArticleDOI
New polymer synthesis by nitroxide mediated living radical polymerizations.
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The physics of block copolymers
TL;DR: The self consistent field theory of block copolymers has been studied in this article, where the authors describe the behavior of blockcopolymers in a variety of ways: 1. Melt Phase Behaviour of Block Copolymers 2. Block copolymer in Dilute Solution 3. Block Copylmers in Semidilute Solution 4.
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Enabling nanotechnology with self assembled block copolymer patterns
TL;DR: In this paper, a review of the current efforts to utilize block copolymers in nanotechnologies including nanostructured membranes, BCP templates for nanoparticle synthesis, photonic crystals, and high-density information storage media is presented.
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The persistent radical effect: a principle for selective radical reactions and living radical polymerizations.
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Controlled/“Living” Radical Polymerization. Kinetics of the Homogeneous Atom Transfer Radical Polymerization of Styrene
TL;DR: The homogeneous atom transfer radical polymerization (ATRP) of styrene using solubilizing 4,4'dialkyl substituted 2,2'bipyridines yielded well-defined polymers with Mw/Mn ≤ 1.10 as mentioned in this paper.