Molecular Semiconductors from Bifunctional Dithia- and Diselenadiazolyl Radicals. Preparation and Solid-State Structural and Electronic Properties of 1,4-[(E2N2C)C6H4(CN2E2)] (E = S, Se)

TLDR: In this paper, the 1,4-phenylene bis(dithiadiazolium) and bis(diselenadiazolinium) dichlorides were shown to be monoclinic, space group P2{sub 1}/n.

Abstract: The reactions of 1,4-phenylenebis(N,N,N{prime}-tris(trimethylsilyl)amidine) with sulfur and selenium dichlorides yield, respectively, the 1,4-phenylenebis(dithiadiazolium) and bis(diselenadiazolium) dichlorides 1,4-((E{sub 2}N{sub 2}C)C{sub 6}H{sub 4}(CN{sub 2}E{sub 2}))Cl{sub 2} (E = S, Se). Reduction of these materials with triphenylantimony affords the corresponding diradical species 1,4-((E{sub 2}N{sub 2}C)C{sub 6}H{sub 4}(CN{sub 2}E{sub 2})), which can be purified by high vacuum sublimation. The crystal structures of 1,4-((E{sub 2}N{sub 2}C)C{sub 6}H{sub 4}(CN{sub 2}E{sub 2})) (E = S, Se) are both monoclinic, space group P2{sub 1}/n. The crystal packing consists of sheets of interleaved columns of weakly associated diradical units (dimers); the mean intradimer separation is 3.34/3.37 {angstrom} (E = S/Se). The sulfur compound is an insulator, but the selenium material has a room temperature pressed pellet resistivity of about 100 {Omega} cm. Magnetic susceptibility measurements show the solids to be predominantly diamagnetic with variable amounts of paramagnetic defects in the lattice. While the exact mechanism of conduction remains to be established, these systems represent the first structurally characterized conducting materials constructed from neutral molecular radicals.