Molecular separation with organic solvent nanofiltration: a critical review.
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This article is published in Chemical Reviews.The article was published on 2014-10-21 and is currently open access. It has received 1167 citations till now. The article focuses on the topics: Nanofiltration.read more
Citations
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Maximizing the right stuff: The trade-off between membrane permeability and selectivity
TL;DR: The permeability/selectivity trade-off is discussed, similarities and differences between synthetic and biological membranes are highlighted, challenges for existing membranes are described, and fruitful areas of future research are identified.
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Sub–10 nm polyamide nanofilms with ultrafast solvent transport for molecular separation
TL;DR: Thin, crumpled polymer films on ceramic supports are high-flux membranes for removing small molecules from organic fluids and were sufficiently rigid that the crumpling textures could withstand pressurized filtration, resulting in increased permeable area.
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Materials for next-generation molecularly selective synthetic membranes
William J. Koros,Chen Zhang +1 more
TL;DR: This Progress Article highlights continuing developments and identifies future opportunities in scalable membrane materials based on rigid, engineered pore structures, for both gas and liquid phase applications.
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Selective Molecular Separation by Interfacially Crystallized Covalent Organic Framework Thin Films
Kaushik Dey,Kaushik Dey,Manas Pal,Kanhu Charan Rout,Shebeeb Kunjattu H,Anuja Das,Rabibrata Mukherjee,Ulhas K. Kharul,Ulhas K. Kharul,Rahul Banerjee,Rahul Banerjee +10 more
TL;DR: This work has demonstrated a bottom-up interfacial crystallization strategy to fabricate these microcrystalline powders as large-scale thin films under ambient conditions, allowing simultaneous control over crystallization and morphology of the framework structure.
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Fundamental transport mechanisms, fabrication and potential applications of nanoporous atomically thin membranes
Luda Wang,Michael S. H. Boutilier,Piran R. Kidambi,Doojoon Jang,Nicolas G. Hadjiconstantinou,Rohit Karnik +5 more
TL;DR: T theoretical and experimental developments in the emerging field of nanoporous atomically thin membranes are discussed, focusing on the fundamental mechanisms of gas- and liquid-phase transport, membrane fabrication techniques and advances towards practical application.
References
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The upper bound revisited
TL;DR: The empirical upper bound relationship for membrane separation of gases initially published in 1991 has been reviewed with the myriad of data now presently available as mentioned in this paper, which indicates a different solubility selectivity relationship for perfluorinated polymers compared to hydrocarbon/aromatic polymers.
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The solution-diffusion model: a review
TL;DR: In this paper, the authors derived the phenomenological equations for transport in these processes using the solution-diffusion model and starting from the fundamental statement that flux is proportional to a gradient in chemical potential.