Moving beyond the Solvent-Tip Approximation to Determine Site-Specific Variations of Interfacial Water Structure through 3D Force Microscopy
Elias Nakouzi,Andrew G. Stack,Sebastien N. Kerisit,Benjamin A. Legg,Benjamin A. Legg,Christopher J. Mundy,Christopher J. Mundy,Gregory K. Schenter,Gregory K. Schenter,Jaehun Chun,Jaehun Chun,James J. De Yoreo,James J. De Yoreo +12 more
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TLDR
Although interfacial solution structure impacts environmental, biological, and technological phenomena, including colloidal stability, protein assembly, heterogeneous nucleation, and water desalina as discussed by the authors, it has not been studied in the literature.Abstract:
Although interfacial solution structure impacts environmental, biological, and technological phenomena, including colloidal stability, protein assembly, heterogeneous nucleation, and water desalina...read more
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Atomically resolved interfacial water structures on crystalline hydrophilic and hydrophobic surfaces
TL;DR: In this paper, the atomic-scale structure of interfacial water on hydrophilic and hydrophobic surfaces was probed using 3D-AFM imaging, and it was shown that hydration layers are formed on both hydrophoric and non-hydrophilic surfaces.
Journal ArticleDOI
Designing Sequence-Defined Peptoids for Biomimetic Control over Inorganic Crystallization
TL;DR: In this paper, the authors discuss the role of peptides and proteins involved in the crystallization process of living organisms, ranging from biomineralization in living organisms to various materials in our lives.
Journal ArticleDOI
Stern and Diffuse Layer Interactions during Ionic Strength Cycling
Emily Ma,Jeongmin Kim,HanByul Chang,Paul E. Ohno,Richard J. Jodts,Thomas F. Miller,Franz M. Geiger +6 more
TL;DR: In this paper, second harmonic generation amplitude and phase measurements are acquired in real time from fused silica: water interfaces that are subjected to ionic strength transitions conducted at pH 5.8.
Journal ArticleDOI
Water Structure in the Electrical Double Layer and the Contributions to the Total Interfacial Potential at Different Surface Charge Densities.
Benjamin Rehl,Emily Ma,Shyam Parshotam,Emma L. DeWalt-Kerian,Tianli Liu,Franz M. Geiger,Julianne M. Gibbs +6 more
TL;DR: In this article , the individual Stern layer and diffuse layer OH stretching spectra at the silica/water interface in the presence of NaCl over a wide pH range using a combination of vibrational sum frequency generation spectroscopy, heterodyned second harmonic generation, and streaming potential measurements.
Journal ArticleDOI
Probing the Structural Details of Chitin Nanocrystal–Water Interfaces by Three‐Dimensional Atomic Force Microscopy
Ayhan Yurtsever,Pei-Xi Wang,Fabio Priante,Ygor Morais Jaques,Kazuki Miyata,Mark J. MacLachlan,Adam S. Foster,Takeshi Fukuda +7 more
TL;DR: In this paper , atomic force microscopy (AFM) images were combined with molecular dynamics simulations to reveal the molecular details of chitin chain arrangements at the surfaces of individual chitIN nanocrystal (chitin NC) surfaces.
References
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Tip dependence of three-dimensional scanning force microscopy images of calcite-water interfaces investigated by simulation and experiments.
Keisuke Miyazawa,John Tracey,Bernhard Reischl,Bernhard Reischl,Peter Spijker,Adam S. Foster,Adam S. Foster,Andrew L. Rohl,Takeshi Fukuma +8 more
TL;DR: The extended STA (E-STA) model allowed us to reveal the strong correlation between the hydration structure just under the tip and the atomic-scale force contrasts, and a method for objectively estimating the similarity between 3D force images was developed.
Journal ArticleDOI
Effect of Hydrophilicity and Interfacial Water Structure on Particle Attachment
TL;DR: Oriented attachment (OA) of nanoparticles is an important and common crystallization pathway as discussed by the authors, but it is difficult to quantify the interparticle forces that underlie OA.
Journal ArticleDOI
Water Structure, Dynamics and Ion Adsorption at the Aqueous {010} Brushite Surface
TL;DR: In this paper, the free energies for the adsorption of several ions on brushite were computed, and the results compared to surface X-ray diffraction data showed that the discrepancy in the surface electron density may be caused by adsoration of excess ions.
Journal ArticleDOI
Solid-Liquid Interface Structure of Muscovite Mica in SrCl2 and BaCl2 Solutions.
Stelian Pintea,Stelian Pintea,Wester de Poel,Aryan E. F. de Jong,Aryan E. F. de Jong,Roberto Felici,Roberto Felici,Elias Vlieg +7 more
TL;DR: The structure of the solid–liquid interface formed by muscovite mica in contact with two divalent ionic solutions (SrCl2 and BaCl2) is determined using in situ surface X-ray diffraction using both specular and non-specular crystal truncation rods to partly agree with previous studies in terms of interface composition.
Journal ArticleDOI
Mineral–Water Interface Structure of Xenotime (YPO4) {100}
Andrew G. Stack,Joanne E. Stubbs,Sriram Goverapet Srinivasan,Santanu Roy,Vyacheslav S. Bryantsev,Peter J. Eng,Radu Custelcean,Alexander D. Gordon,Cole R. Hexel +8 more
TL;DR: In this article, the atomic structure of the mineral-water interface of the {100} surface of Xenotime (nominally YPO4) was determined using the truncation rod (CTR) measurements and density functional theory (DFT) calculations.
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