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Multinuclear solid-state NMR of inorganic materials
TLDR
In this article, the authors present a review of the NMR of low-gamma nuclides and other spin-1/2 nuclei, as well as other quadrupolar nuclei.Abstract:
Chapter headings. Preface. Introduction. Physical background. Experimental approaches. 29Si NMR. 27Al NMR. 17O NMR. NMR of other commonly studied nuclei. NMR of low-gamma nuclides. NMR of other spin-1/2 nuclei. NMR of other quadrupolar nuclei. Solid state NMR of metals and alloys.read more
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Origin of additional capacities in metal oxide lithium-ion battery electrodes
Yan-Yan Hu,Zigeng Liu,Kyung-Wan Nam,Olaf J. Borkiewicz,Jun Cheng,Xiao Hua,Matthew T. Dunstan,Xiqian Yu,Kamila M. Wiaderek,Lin-Shu Du,Karena W. Chapman,Peter J. Chupas,Xiao-Qing Yang,Claire P. Grey,Claire P. Grey +14 more
TL;DR: High-resolution multinuclear/multidimensional solid-state NMR techniques are used with in situ synchrotron-based techniques to study the prototype conversion material RuO2, demonstrating a protocol for studying the structure and spatial proximities of nanostructures formed in this system, including the amorphous solid electrolyte interphase that grows on battery electrodes.
Journal ArticleDOI
NMR reveals the surface functionalisation of Ti3C2 MXene
Michael A. Hope,Alexander C. Forse,Kent J. Griffith,Maria R. Lukatskaya,Michael Ghidiu,Yury Gogotsi,Clare P. Grey +6 more
TL;DR: The internal surface terminations of Ti3C2Tx MXene are identified and quantified and there are found to be significantly fewer -OH terminations than -F and -O, with the proportions highly dependent on the synthesis method.
Journal ArticleDOI
Lithium salts as “redox active” p-type dopants for organic semiconductors and their impact in solid-state dye-sensitized solar cells
Antonio Abate,Tomas Leijtens,Sandeep Pathak,Joël Teuscher,Roberto Avolio,Maria Emanuela Errico,James Kirkpatrik,James M. Ball,Pablo Docampo,Ian J. McPherson,Henry J. Snaith +10 more
TL;DR: The doping mechanism consumes Li(+) during the device operation, which poses a problem, since the lithium salt is required at the dye-sensitized heterojunction to enhance charge generation, and highlights that new additives are required to maximize the performance and the long-term stability of ss-DSSCs.
Journal ArticleDOI
Al environment in tectosilicate and peraluminous glasses: A 27Al MQ-MAS NMR, Raman, and XANES investigation
TL;DR: In this paper, the structure of tecto-aluminosilicate and peraluminous glasses were studied using Raman spectroscopy, X-ray absorption at the Al K-edge and 27Al NMR spectrograms with two different high fields (400 and 750 MHz).
Journal ArticleDOI
Al coordination and speciation in calcium aluminosilicate glasses: Effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy
TL;DR: In this article, the structure and properties of glasses and melts in the CaO-Al2O3-SiO2 (CAS) system were investigated using Raman spectroscopy and 27Al Nuclear Magnetic Resonance on CAS glasses obtained by classic and rapid quenching methods.
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