Journal ArticleDOI
Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts
Nfflria Huguet,Ivana Jevtovikj,Alvaro Gordillo,Michal Lejkowski,Ronald Lindner,Miriam Bru,Andrey Y. Khalimon,Frank Rominger,Stephan Andreas Schunk,Peter Hofmann,Michael Limbach,Michael Limbach +11 more
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TLDR
The nickel-catalyzed direct carboxylation of alkenes with the cheap and abundantly available C1 building block carbon dioxide (CO2) in the presence of a base has been achieved and it is possible, in one step, to synthesize sodium acrylate from ethylene, CO2 , and a sodium salt.Abstract:
The nickel-catalyzed direct carboxylation of alkenes with the cheap and abundantly available C1 building block carbon dioxide (CO2 ) in the presence of a base has been achieved. The one-pot reaction allows for the direct and selective synthesis of a wide range of α,β-unsaturated carboxylates (TON>100, TOF up to 6 h(-1) , TON=turnover number, TOF=turnover frequency). Thus, it is possible, in one step, to synthesize sodium acrylate from ethylene, CO2 , and a sodium salt. Acrylates are industrially important products, the synthesis of which has hitherto required multiple steps.read more
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Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment
Jens Artz,Thomas Müller,Katharina Thenert,Johanna Kleinekorte,Raoul Meys,André Dirk Sternberg,André Bardow,Walter Leitner,Walter Leitner +8 more
TL;DR: The motivation to develop CO2-based chemistry does not depend primarily on the absolute amount of CO2 emissions that can be remediated by a single technology and is stimulated by the significance of the relative improvement in carbon balance and other critical factors defining the environmental impact of chemical production in all relevant sectors in accord with the principles of green chemistry.
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Transition-Metal-Catalyzed Carboxylation Reactions with Carbon Dioxide.
TL;DR: It is indicated that catalytic carboxylation reactions have entered a new era of exponential growth, evolving into a mature discipline that allows for streamlining the synthesis of carboxylic acids, building blocks of utmost relevance in industrial endeavors.
Journal ArticleDOI
State of the art and perspectives in catalytic processes for CO2 conversion into chemicals and fuels: The distinctive contribution of chemical catalysis and biotechnology
TL;DR: In this paper, the state of the art in CO 2 conversion and a perspective on the potential of such technology is given. But, as stated in the paper, "each atom of C we can recycle is an atom of fossil carbon left in the underground for next generations that will not reach the atmosphere today" and "the need to reduce the emission of carbon dioxide into the atmosphere is pushing toward the use of renewable carbon".
Journal ArticleDOI
The Use of Carbon Dioxide (CO2) as a Building Block in Organic Synthesis from an Industrial Perspective
Saumya Dabral,Thomas Schaub +1 more
Journal ArticleDOI
Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis
TL;DR: The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO2 has been developed using photoredox catalysis in continuous flow using a range of functionalized terminal styrens.
References
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Catalysis for the valorization of exhaust carbon: from CO2 to chemicals, materials, and fuels. technological use of CO2.
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Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?
TL;DR: This Review presents an overview of the available homogeneous catalytic routes that use carbon dioxide as a C(1) carbon source for the synthesis of industrial products as well as fine chemicals.
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Worldwide innovations in the development of carbon capture technologies and the utilization of CO2
Peter Markewitz,Wilhelm Kuckshinrichs,Walter Leitner,Walter Leitner,Jochen Linssen,Petra Zapp,Richard Bongartz,Andrea Schreiber,Thomas Müller +8 more
TL;DR: In this article, the authors compare the status of three main lines of CCS technologies with respect to efficiency, energy consumption, and technical feasibility as well as the implications of the CCS on the efficiency and structure of the energy supply chain.
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Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes
TL;DR: Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst, resulting in potassium formate obtaining the highest values reported to date.
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Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxide
TL;DR: This critical review summarizes the recent advances on transition-metal-catalyzed C-C bond formation through the fixation of carbon dioxide and their synthetic applications.