Journal ArticleDOI
One-Pot Synthesis of Symmetrical Diaryl Trithiocarbonates through Copper-Catalyzed Coupling of Aryl Compounds, Sodium Sulfide, and Carbon Disulfide†
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TLDR
In this paper, a method for the synthesis of symmetrical diaryl trithiocarbonates through the one-pot copper-catalyzed coupling reaction of sodium sulfide, carbon disulfide, and aryl compounds in DMF solution is presented.About:
This article is published in European Journal of Organic Chemistry.The article was published on 2013-01-01. It has received 21 citations till now. The article focuses on the topics: Aryl & Sodium sulfide.read more
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Synthesis and characterization of magnetic copper ferrite nanoparticles and their catalytic performance in one-pot odorless carbon-sulfur bond formation reactions
TL;DR: In this paper, a catalytic application of copper ferrite nanoparticles (CuFe 2 O 4 ) for one-pot odorless production of aryl alkyl thioethers using thiourea and bromides in wet polyethylene glycol as a green solvent was introduced.
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One-pot synthesis of aryl alkyl thioethers and diaryl disulfides using carbon disulfide as a sulfur surrogate in the presence of diethylamine catalyzed by copper(I) iodide in polyethylene glycol (PEG200)
TL;DR: In this paper, a copper catalyzed one-pot protocol for the preparation of aryl alkyl thioethers and diaryl disulfides using carbon disulfide as the sulfur source and diethylamine in polyethylene glycol (PEG200) is described.
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Copper(I) iodide catalyzes odorless thioarylation of phenolic esters with alkyl derivatives using thiourea in wet polyethylene glycol (PEG 200)
TL;DR: In this article, a useful catalytic application of copper(I) iodide for one pot odor-free generation of unsymmetrical aryl alkyl thioethers was presented.
Journal ArticleDOI
Transition-Metal-Catalyzed C-S, C-Se, and C-Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges.
TL;DR: In this article , the authors discuss recent progress in the field of C-Z bond formation reactions (Z = S, Se, Te) catalyzed by transition metals and discuss the key achievements, problems, and challenges for this field.
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Recent Achievements in Organic Trithiocarbonates Synthesis
TL;DR: A number of synthetic procedures for the synthesis of trithiocarbonates have been proposed over the last few years as discussed by the authors, but none of them have yet been evaluated in the real world.
References
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Journal ArticleDOI
Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions
Journal ArticleDOI
Living free radical polymerization with reversible addition : fragmentation chain transfer (the life of RAFT)
Graeme Moad,John Chiefari,Y. K. Chong,Julia Krstina,Roshan T. A. Mayadunne,Almar Postma,Ezio Rizzardo,San H. Thang +7 more
TL;DR: In this article, free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization) is discussed with a view to answering the following questions: (a) How living is RAFT polymerization? (b) What controls the activity of thiocarbonylthio compounds in RAFT polymers, and (c) How do rates of polymerization differ from those of conventional radical polymerisation? (d) Can RAFT agents be used in emulsion polymerization; and (e) Retardation, observed when high concentra-
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Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization) Using Dithiocarbamates as Chain Transfer Agents
TL;DR: In this article, the nonbonded electron pair of the nitrogen included as part of an aromatic system was used as an additive component for living radical polymerization with reversible addition−fragmentation chain transfer.
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A novel synthesis of functional dithioesters, dithiocarbamates, xanthates and trithiocarbonates
TL;DR: In this article, a novel synthesis of functional dithioesters, dithiocarbamates, xanthates and trithiocalarbonates is described, which is compatible with a wide range of functionalities (e.g. carboxy, hydroxy and nitrile).
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Novel p-arylthio cinnamides as antagonists of leukocyte function-associated antigen-1/intracellular adhesion molecule-1 interaction. 2. Mechanism of inhibition and structure-based improvement of pharmaceutical properties.
Gang Liu,Jeffrey R. Huth,Edward T. Olejniczak,Renaldo Mendoza,Devries Peter J,Sandra Leitza,Edward B. Reilly,Gregory F. Okasinski,Stephen W. Fesik,Thomas W. von Geldern +9 more
TL;DR: A fragment-based NMR screening strategy was applied to identify small, more water-soluble ligands that bind to a specific region of the IDAS of LFA-1 and the resulting analogues exhibited increased aqueous solubility and improved pharmacokinetic profiles in rats, demonstrating the power of this NMR-based screening approach for rapidly modifying high-affinity ligands.