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Oxo and nitrido complexes of molybdenum, tungsten, rhenium, and osmium. a theoretical study

Arndt Neuhaus, +2 more
- 01 Nov 1994 - 
- Vol. 33, Iss: 23, pp 5278-5286
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This article is published in Inorganic Chemistry.The article was published on 1994-11-01. It has received 63 citations till now. The article focuses on the topics: Rhenium & Molybdenum.

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Triple-Bond Covalent Radii

TL;DR: A system of additive covalent radii is proposed for sigma(2) pi(4) triple bonds involving elements from Be to E 112 (eka-mercury) and borderline cases with weak multiple bonding are included.
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Synthesis of crystalline metal nitride and metal carbide nanostructures by sol-gel chemistry

TL;DR: In this article, a review of sol-gel-based pathways for the synthesis of metal nitride and carbide nanoparticles is presented, with an overview of the potentialities of these still hardly touched materials.
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Structure and Bonding of the Transition-Metal Carbonyl Complexes M(CO)5L (M = Cr, Mo, W) and M(CO)3L (M = Ni, Pd, Pt; L = CO, SiO, CS, N2, NO+, CN-, NC-, HCCH, CCH2, CH2, CF2, H2)1

TL;DR: In this paper, the (CO)nM−L bond dissociation energies at CCSD(T)/II using MP2/II optimized geometries also agree quite well with experimental data.
Journal ArticleDOI

Low valent aluminum and gallium compounds — structural variety and coordination modes to transition metal fragments

TL;DR: The chemistry of low valent aluminum and gallium compounds is a very topical area of research as discussed by the authors, which requires new insight on the description of chemical bonds, and not only the routes to these compounds and their structures described here, but thoughts on their description of bonding are presented as well.
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Computational studies of transition metal-main group multiple bonding.

TL;DR: The diversity of TMdMG chemistry has made it a fruitful area in the search for novel inorganic structure and reactivity and it has emerged that this chemical diversity provides a rigorous challenge in the development of more efficient and reliable techniques for modeling of inorganic and organometallic chemistry.
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