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Palladium-catalyzed cross-coupling reactions of organoboron compounds

Norio Miyaura, +1 more
- 01 Nov 1995 - 
- Vol. 95, Iss: 7, pp 2457-2483
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TLDR
In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
Abstract
B. Other Catalyti; Process by Transition-Metal Complexes IV. Cross-Coupling Reaction A. Coupling of 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6. Coupling of Arylboron Derivatives: Synthesis of Biaryls C. Coupling of Alkylboron Derivatives D. Coupling with Triflates E. Synthesis of Vinylic Sulfides F. Coupling with lodoalkanes: Alkyl-Alkyl CouDlino G. Coupling with Other Organic Halides and Boron Reagents V. Head-to-Tail Coupling VI. Carbonylative Coupling VII. Alkoxycarbonylation and Dimerization VIII. Conclusion 2457 2458 2458

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Journal ArticleDOI

A Valuable, Inexpensive CuI/N-Heterocyclic Carbene Catalyst for the Selective Diboration of Styrene

TL;DR: DFT calculations suggest that no oxidative addition processes take place at copper, but that intermediates containing coordinated sigma-bonds are involved in the catalytic cycle.
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Syntheses of Isochromenes and Naphthalenes by Electrophilic Cyclization of Acetylenic Arenecarboxaldehydes

TL;DR: Highly substituted 1H-isochromenes, isobenzofurans, and pyranopyridines can be prepared by allowing o-(1-alkynyl)arenecarboxaldehydes and ketones to react with I2, ICl, NIS, Br2, NBS, p-O2NC6H4SCl, or PhSeBr and various alcohols or carbon-based nucleophiles at room temperature.
Journal ArticleDOI

Recent advances in the direct functionalization of quinoxalin-2(1H)-ones.

TL;DR: This review will focus on the recent achievements, mainly including arylation, alkylation, acylation, alkoxycarbonylation, amination, amidation and phosphonation of quinoxalin-2(1H)-ones.
Journal ArticleDOI

A computational study of phosphine ligand effects in Suzuki-Miyaura coupling

TL;DR: In this paper, the full catalytic cycle of the Suzuki-Miyaura coupling between PhBr and PhB(OH)3− with four different palladium monophosphine catalysts derived from Pd(PMe3)2, PdP(CF3)3), PdPh3, PhPh3 and PdpBu3 were explored and the differences between the ligands have been analyzed.
Journal ArticleDOI

Computational study of the transmetalation process in the Suzuki–Miyaura cross-coupling of aryls

TL;DR: In this paper, the transmetalation step of the Suzuki-Miyaura cross-coupling between aryl groups is analyzed by means of DFT calculations with the Becke3LYP functional.
References
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Journal ArticleDOI

Comprehensive Organometallic Chemistry

Dietmar Seyferth
- 01 Jul 1984 - 
BookDOI

The chemistry of organic silicon compounds

TL;DR: A.R.Bassindale and P.G.Taylor as mentioned in this paper discussed the photochemistry of organosilicon compounds, A.R., B.B.Birkofer and O.Ojima.
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