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Palladium-catalyzed cross-coupling reactions of organoboron compounds

Norio Miyaura, +1 more
- 01 Nov 1995 - 
- Vol. 95, Iss: 7, pp 2457-2483
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TLDR
In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
Abstract
B. Other Catalyti; Process by Transition-Metal Complexes IV. Cross-Coupling Reaction A. Coupling of 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6. Coupling of Arylboron Derivatives: Synthesis of Biaryls C. Coupling of Alkylboron Derivatives D. Coupling with Triflates E. Synthesis of Vinylic Sulfides F. Coupling with lodoalkanes: Alkyl-Alkyl CouDlino G. Coupling with Other Organic Halides and Boron Reagents V. Head-to-Tail Coupling VI. Carbonylative Coupling VII. Alkoxycarbonylation and Dimerization VIII. Conclusion 2457 2458 2458

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π-building blocks for organic electronics: Revaluation of "inductive" and "resonance" Effects of π-electron deficient units

TL;DR: In this article, a review of π-building blocks for semiconducting polymers and oligomers, especially electron poor heterocycles (acceptor units), focusing on the model compounds and the corresponding polymers, is presented.
Journal ArticleDOI

Highly polarized blue electroluminescence from homogeneously aligned films of poly(9,9-dioctylfluorene)

TL;DR: In this paper, the alignment of poly(9,9-dioctylfluorene) films on thin layers of rubbed precursor-route poly(p-phenylenevinylene) allows the construction of light-emitting diodes that emit highly polarized blue light (λem=458nm).
Journal ArticleDOI

Industrial R&D on Catalytic CC and CN Coupling Reactions: A Personal Account on Goals, Approaches and Results

TL;DR: In this paper, the authors focus on finding shorter routes to target molecules using catalytic methods, and development of industrial catalytic processes in multi-step syntheses, in order to find shorter routes.
Journal ArticleDOI

Synthesis and characterization of a new light-emitting fluorene-thieno[3,2-b]thiophene-based conjugated copolymer

TL;DR: In this paper, a new alternating polyfluorene copolymer, poly(9,9‘-dioctylfluorene-alt-thieno[3,2-b]thiophene) (PFTT), containing a thiophene-condensed thieno [3, 2-b]-stiophene moiety has been synthesized via a palladium-catalyzed Suzuki coupling reaction.
Journal ArticleDOI

Cross-coupling reactions with boronic acids in water catalysed by oxime-derived palladacycles

TL;DR: Palladacycles derived from phenone-oximes 1 are efficient precatalysts for the Suzuki-Miyaura coupling of arylboronic acids with aromatic and heteroaromatic bromides and chlorides under water reflux under aerobic conditions.
References
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Journal ArticleDOI

Comprehensive Organometallic Chemistry

Dietmar Seyferth
- 01 Jul 1984 - 
BookDOI

The chemistry of organic silicon compounds

TL;DR: A.R.Bassindale and P.G.Taylor as mentioned in this paper discussed the photochemistry of organosilicon compounds, A.R., B.B.Birkofer and O.Ojima.
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