Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
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In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.Abstract:
B. Other Catalyti; Process by Transition-Metal Complexes IV. Cross-Coupling Reaction A. Coupling of 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6. Coupling of Arylboron Derivatives: Synthesis of Biaryls C. Coupling of Alkylboron Derivatives D. Coupling with Triflates E. Synthesis of Vinylic Sulfides F. Coupling with lodoalkanes: Alkyl-Alkyl CouDlino G. Coupling with Other Organic Halides and Boron Reagents V. Head-to-Tail Coupling VI. Carbonylative Coupling VII. Alkoxycarbonylation and Dimerization VIII. Conclusion 2457 2458 2458read more
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Efficient blue-emitting silafluorene–fluorene-conjugated copolymers: selective turn-off/turn-on detection of explosives
TL;DR: In this article, the synthesis and spectroscopic characterization of a series of new blue-emitting silafluorene-fluorene copolymers is described, which are synthesized using kinetically controlled hydrosilylation copolymerization of 1,1-dihydridosilafluoresne with a series 9-substituted 2,7-diethynylfluorenes.
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Decarboxylative cross-coupling of aryl tosylates with aromatic carboxylate salts.
TL;DR: The redox-neutral decarboxylative coupling reactions that have been developed in the research group aim at replacing sensitive and costly organometallic reagents, which are traditionally used as nucleophilic coupling partners, with stable, inexpensive and widely available carboxylate salts.
Journal ArticleDOI
Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki-Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations
TL;DR: In this article, the Suzuki−Miyaura process with Pd(OAc)2 and KenPhos as ligand was used to synthesize axially chiral biaryl amides.
Book ChapterDOI
Transition-metal systems bearing a nucleophilic carbene ancillary ligand : from thermochemistry to catalysis
Laleh Jafarpour,Steven P. Nolan +1 more
TL;DR: In this article, the enthalpies of reaction for nucleophilic carbenes depend on the stereoelectronic properties of the ligands affecting the availability of the carbene lone pair.
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The chemistry of organic silicon compounds
Zvi Rappoport,Yitzhak Apeloig +1 more
TL;DR: A.R.Bassindale and P.G.Taylor as mentioned in this paper discussed the photochemistry of organosilicon compounds, A.R., B.B.Birkofer and O.Ojima.