Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
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TLDR
In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.Abstract:
B. Other Catalyti; Process by Transition-Metal Complexes IV. Cross-Coupling Reaction A. Coupling of 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6. Coupling of Arylboron Derivatives: Synthesis of Biaryls C. Coupling of Alkylboron Derivatives D. Coupling with Triflates E. Synthesis of Vinylic Sulfides F. Coupling with lodoalkanes: Alkyl-Alkyl CouDlino G. Coupling with Other Organic Halides and Boron Reagents V. Head-to-Tail Coupling VI. Carbonylative Coupling VII. Alkoxycarbonylation and Dimerization VIII. Conclusion 2457 2458 2458read more
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Palladiumkatalysierte Carbonylierungen von Arylhalogeniden und ähnlichen Substraten
TL;DR: In this article, eine CO-Gruppe reicher: (Hetero-)Arene sind aus der industriellen Herstellung von Agrochemikalien, Farbstoffen, Pharmaka etc. nicht wegzudenken.
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Formation of Aryl‐ and Benzylboronate Esters by Rhodium‐Catalyzed C−H Bond Functionalization with Pinacolborane
TL;DR: Direct borylation of C-H bonds in aromatic compounds can be achieved by using the efficient homogeneous catalyst precursor [RhCl(PiPr3 )2 (N2 )] and pinacolborane (HBpin; see scheme).
Journal ArticleDOI
Metal-organic frameworks catalyzed C-C and C-heteroatom coupling reactions.
TL;DR: The use of MOFs as catalysts to promote cross-coupling reactions involving organometallic reaction intermediates and catalysis by Lewis acid sites, which are of large synthetic utility due to the high yields achieved, mild conditions and compatibility with other functional groups.
Journal ArticleDOI
Metal-catalyzed reactions of diborons for synthesis of organoboron compounds
Tatsuo Ishiyama,Norio Miyaura +1 more
TL;DR: Direct C-H borylation of arenes catalyzed by a transition metal complex was studied as an economical protocol for the synthesis of a variety of arylboron derivatives.
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Standing on the shoulders of Hermann Staudinger: Post-polymerization modification from past to present
TL;DR: A broad overview of the development and evolution of post-polymerization modification reactions can be found in this paper, where the authors provide an overview of eight main classes of reactions.
References
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The chemistry of organic silicon compounds
Zvi Rappoport,Yitzhak Apeloig +1 more
TL;DR: A.R.Bassindale and P.G.Taylor as mentioned in this paper discussed the photochemistry of organosilicon compounds, A.R., B.B.Birkofer and O.Ojima.