Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
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In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.Abstract:
B. Other Catalyti; Process by Transition-Metal Complexes IV. Cross-Coupling Reaction A. Coupling of 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6. Coupling of Arylboron Derivatives: Synthesis of Biaryls C. Coupling of Alkylboron Derivatives D. Coupling with Triflates E. Synthesis of Vinylic Sulfides F. Coupling with lodoalkanes: Alkyl-Alkyl CouDlino G. Coupling with Other Organic Halides and Boron Reagents V. Head-to-Tail Coupling VI. Carbonylative Coupling VII. Alkoxycarbonylation and Dimerization VIII. Conclusion 2457 2458 2458read more
Citations
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Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms
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Mercaptopropyl-Modified Mesoporous Silica: A Remarkable Support for the Preparation of a Reusable, Heterogeneous Palladium Catalyst for Coupling Reactions
TL;DR: The functionalization of SBA-15 with mercaptopropyl trimethoxysilane leads to a material capable of absorbing Pd from organic and aqueous solutions, illustrating the importance of the thiol ligand to retain Pd on the surface.
Journal ArticleDOI
Sterically demanding, bioxazoline-derived N-heterocyclic carbene ligands with restricted flexibility for catalysis.
TL;DR: A unique family of N-heterocyclic carbenes derived from bioxazolines suitable for application in transition-metal catalysis is described, and for the first time, tetraortho-substituted biaryls with methyl and larger ortho- substituents have been synthesized from aryl chlorides using the Suzuki-Miyaura method.
Journal ArticleDOI
Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity
TL;DR: This review summarizes the most significant developments in the area of C-O bond-cleavage when employing aryl or vinyl ethers, providing a detailed overview of the current state of the art and including future aspects, when applicable.
Journal ArticleDOI
Rhodium-Catalyzed Conjugate Addition of Aryl- or 1-Alkenylboronic Acids to Enones
TL;DR: In this paper, the rhodium(I)-catalyzed conjugate addition of aryl-or 1-alkenylboronic acids to enones was carried out in high yields at 50 °C in an aqueous solvent.
References
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The chemistry of organic silicon compounds
Zvi Rappoport,Yitzhak Apeloig +1 more
TL;DR: A.R.Bassindale and P.G.Taylor as mentioned in this paper discussed the photochemistry of organosilicon compounds, A.R., B.B.Birkofer and O.Ojima.