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Journal ArticleDOI

Peroxo complexes of titanium

Gerold Schwarzenbach, +2 more
- 01 Nov 1970 - 
- Vol. 9, Iss: 11, pp 2381-2390
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This article is published in Inorganic Chemistry.The article was published on 1970-11-01. It has received 228 citations till now. The article focuses on the topics: Titanium.

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Novel Approach for Enhanced Scandium and Titanium Leaching Efficiency from Bauxite Residue with Suppressed Silica Gel Formation.

TL;DR: A novel leaching process based on oxidative leaching conditions, aiming more efficient and selective leaching but also considering environmental aspects via lower acid consumption, was investigated in this study.
Journal ArticleDOI

Solvothermal Synthesis of TiO2 Nanocrystal Colloids from Peroxotitanate Complex Solution and Their Photocatalytic Activities

TL;DR: In this article, a peroxotitanate complex solution starting from titanium(IV) sulfate and hydrogen peroxide (H2O2) in water/alcohol media by a solvothermal process was used to obtain a highly crystallized anatase phase.
Journal ArticleDOI

Synthesis and O2 Reactivity of a Titanium(III) Metal-Organic Framework.

TL;DR: Through a combination of gas adsorption, X-ray diffraction, magnetic susceptibility, and electronic and vibrational spectroscopy measurements, this high-surface-area framework is shown to contain five-coordinate Ti(III) centers upon desolvation, which irreversibly bind O2 to form titanium(IV) superoxo and peroxo species.
Journal ArticleDOI

Facile Preparation of Hierarchical TiO2 Nano Structures: Growth Mechanism and Enhanced Photocatalytic H2 Production from Water Splitting Using Methanol as a Sacrificial Reagent

TL;DR: Self-assembled hierarchical titania nanostructures exhibited much superior photocatalytic activity compared to that of starting material, i.e., TiO2-Memb.
Journal ArticleDOI

Formation of zirconium titanate powder from a sol-gel prepared reactive precursor

TL;DR: In this article, a hydroxoperoxo compound of Zr and Ti (HXPZT) was prepared as a reactive powder by a sol-gel method, and X-ray diffraction and SEM studies showed it was formed from small (ca. 10-15 μm) amorphous particles.
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