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Journal ArticleDOI

Peroxo complexes of titanium

Gerold Schwarzenbach, +2 more
- 01 Nov 1970 - 
- Vol. 9, Iss: 11, pp 2381-2390
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This article is published in Inorganic Chemistry.The article was published on 1970-11-01. It has received 228 citations till now. The article focuses on the topics: Titanium.

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Synthesis of tapered tetragonal nanorods of anatase TiO2 with enhanced photocatalytic activity via a sol–hydrothermal process mediated by H2O2 and NH3

TL;DR: In this article, a series of tapered tetragonal nanorods of anatase TiO2 enclosed by both high-energy and low-energy facets were fabricated via a facile sol-hydrothermal approach that is free of organic additives and erosive HF reagents.
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Resonance Raman studies of the peroxotitanate(IV) complexes K2(Ti(O2)(SO4)2)·5H2O and K2(Ti(O2)(C2O4)2)·3H2O

TL;DR: In this article, the resonance Raman spectra of K 2 (Ti(O 2 )(SO 4 ) 2 )·5H 2 O 2 O and K 2 K 2 O(C 2 O 4 )2 )·3 H 2 O are recorded.
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Water-soluble polymer anchored peroxotitanates as environmentally clean and recyclable catalysts for mild and selective oxidation of sulfides with H2O2 in water

TL;DR: In this article, a pair of new, water-tolerant and recyclable catalysts of the type [Ti2(O2)2O2(OH)2]4-L (L ǫ=‡PA or PMA), highly effective in chemoselective sulfoxidation of organic sulfides with 30% H 2O2 in aqueous medium at ambient temperature.
Journal ArticleDOI

A new method of making titania gels and their microstructure

TL;DR: The reaction of H2O2 with alkoxides results in aerohydro gels of titania as mentioned in this paper, which appear to form by a complex polymerization process involving peroxy species.
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Preparation of uniform submicrometer particles of calcium titanate and lead niobate by replacement reactions

TL;DR: In this article, the authors proposed a method to obtain uniform submicrometer particles of calcium titanium peroxo-hydroxide by adding calcium salts to the solution of peroxotitaniun.
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