Journal ArticleDOI
Picosecond proton transfer studies in water-alcohols solutions
Dan Huppert,E. Kolodney +1 more
TLDR
In this paper, it was found that the rate of proton transfer decreases more rapidly in water propanol solutions than in water ethanol solutions, which can be interpreted in terms of water breaking structure by the organic solvent.About:
This article is published in Chemical Physics.The article was published on 1981-12-15. It has received 59 citations till now. The article focuses on the topics: Propanol & Picosecond.read more
Citations
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Journal ArticleDOI
Excited-state proton transfer reactions I. Fundamentals and intermolecular reactions
TL;DR: Theoretical models that have been proposed and applied to proton transfer reactions are reviewed in this paper, where simple models, like the Eigen model, Marcus theory and the intersecting state model, are applied to excited-state intermolecular proton transfers.
Journal ArticleDOI
Geminate recombination in excited-state proton-transfer reactions: Numerical solution of the Debye-Smoluchowski equation with backreaction and comparison with experimental results
Ehud Pines,D. Huppert,Noam Agmon +2 more
TL;DR: In this paper, the Debye-smoluchowski equation is solved numerically with boundary conditions which account for the reversibility of the reaction, and the intrinsic rate constants are used to predict steady-state rates, yields, and pK values, in agreement with experiment.
Clustering of water on hydrated protons in a supersonic free jet expansion
J. Q. Searcy,J. B. Fenn +1 more
TL;DR: In this article, the size distribution and growth in the gas phase of ions in the series H+(H2O)n were investigated. But the results were limited to n = 28.
Journal ArticleDOI
The dynamic aspects of proton transfer processes
Menachem Gutman,Esther Nachliel +1 more
Journal ArticleDOI
Photochemistry of “Super” Photoacids. 2. Excited-State Proton Transfer in Methanol/Water Mixtures
TL;DR: In this article, the time-resolved fluorescence data fit the solution of the Debye−Smoluchowski equation for the reversible geminate recombination of ions over the whole range of methanol/water concentration ratios.
References
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Book
CRC Handbook of Chemistry and Physics
TL;DR: CRC handbook of chemistry and physics, CRC Handbook of Chemistry and Physics, CRC handbook as discussed by the authors, CRC Handbook for Chemistry and Physiology, CRC Handbook for Physics,
Journal ArticleDOI
Improved simulation of liquid water by molecular dynamics
TL;DR: In this paper, a four-charge model for each molecule and a modification of the prior ''BNS'' interaction was proposed to improve the fidelity of the molecular dynamics simulation, leading to a density maximum near 27°C for the liquid in coexistence with its vapor and to molecular distribution functions in better agreement with x-ray scattering experiments.
Journal ArticleDOI
Liquid Water: Molecular Correlation Functions from X‐Ray Diffraction
A. H. Narten,H. A. Levy +1 more
TL;DR: For nearly spherical molecules, the x-ray scattering from liquids yields structure and correlation functions for molecular scattering centers as discussed by the authors, which provide a sensitive test for future work on a molecular theory of liquid water.
Book ChapterDOI
Acid-Base Properties of Electronically Excited States of Organic Molecules
J.F. Ireland,P. A. H. Wyatt +1 more
TL;DR: In this paper, the acid-base properties of electronically excited states of organic molecules are discussed and the effects of solvation on 0-0 energies are discussed. And the changes in molecular fluorescence with acidity give information about the protolytic behavior of the excited singlet state of a compound.
Related Papers (5)
Acid-Base Properties of Electronically Excited States of Organic Molecules
J.F. Ireland,P. A. H. Wyatt +1 more
Geminate recombination in excited-state proton-transfer reactions: Numerical solution of the Debye-Smoluchowski equation with backreaction and comparison with experimental results
Ehud Pines,D. Huppert,Noam Agmon +2 more