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Journal ArticleDOI

Polymers from Renewable Resources: A Challenge for the Future of Macromolecular Materials

Alessandro Gandini
- 14 Oct 2008 - 
- Vol. 41, Iss: 24, pp 9491-9504
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TLDR
In this article, the state of the art regarding the field of polymers from renewable resources is examined and a critical appraisal of the situation related to a representative number of specific materials, in terms of their interest, present degree of advancement, and prospective development within short and medium-term projections.
Abstract
This perspective article examines the state of the art regarding the field of polymers from renewable resources and attempts to give a critical appraisal of the situation related to a representative number of specific materials, in terms of their interest, present degree of advancement, and prospective development within short- and medium-term projections. The selected examples include polysaccharides and their derivatives, lignin, suberin, vegetable oils, tannins, natural monomers like terpenes, and monomers derived from sugars, with particular emphasis on furan derivatives and lactic acid, bacterial cellulose, and poly(hydroxyalkanoates), ending with a brief assessment of the potential role of glycerol and ethanol as future precursors to monomers.

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Journal ArticleDOI

Green Chemistry: Principles and Practice

TL;DR: The concepts of design and the scientific philosophy of Green Chemistry are covered with a set of illustrative examples and the challenge of using the Principles as a cohesive design system is discussed.
Journal ArticleDOI

Lignin as Renewable Raw Material

TL;DR: For value-added applications of lignin to be improved, medium- and long-term conversion technologies must be developed, especially for the preparation of low-molecular-weight compounds as an alternative to the petrochemical industry.
Journal ArticleDOI

Biomass into chemicals: Conversion of sugars to furan derivatives by catalytic processes

TL;DR: Werpy et al. as mentioned in this paper reviewed the catalytic routes for the synthesis of 5-HMF, 2-5-FDCA, 2,5-DMF and other furanic derivatives from sugar.
Journal ArticleDOI

50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers

TL;DR: In this article, the authors highlight five research topics, including the synthesis of renewable monomers and degradable polymers, the development of chemical recycling strategies, new classes of reprocessable thermosets, and the design of advanced catalysts.
Journal ArticleDOI

The irruption of polymers from renewable resources on the scene of macromolecular science and technology

TL;DR: A panoramic overview of recent progress in the most relevant areas related to such materials, including the polymerisation of natural monomers and their derivatives, the exploitation of biopolymers, as such, or after appropriate modifications, as well as the preparation of composites and blends, can be found in this article.
References
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Journal ArticleDOI

Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering.

TL;DR: Hydrogen Production by Water−Gas Shift Reaction 4056 4.1.
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Chitin and chitosan: Properties and applications

TL;DR: Chitin is the second most important natural polymer in the world as mentioned in this paper, and the main sources of chitin are two marine crustaceans, shrimp and crabs, which are used for food, cosmetics, biomedical and pharmaceutical applications.
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Cellulose: Fascinating Biopolymer and Sustainable Raw Material

TL;DR: The current knowledge in the structure and chemistry of cellulose, and in the development of innovative cellulose esters and ethers for coatings, films, membranes, building materials, drilling techniques, pharmaceuticals, and foodstuffs are assembled.
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The path forward for biofuels and biomaterials

TL;DR: The integration of agroenergy crops and biorefinery manufacturing technologies offers the potential for the development of sustainable biopower and biomaterials that will lead to a new manufacturing paradigm.
Journal ArticleDOI

Chemical Routes for the Transformation of Biomass into Chemicals

TL;DR: Dehydroisomerization of Limonene and Terpenes To Produce Cymene 2481 4.2.1.
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