Journal ArticleDOI
Preparation and DC conductivity of an amorphous organic semiconducting system
TLDR
A series of semiconducting samples with non-crystalline structure was prepared by the thermal degradation of phenol formaldehyde resin at different heat treatment temperatures as discussed by the authors, and DC measurements on these organic materials yield an interesting extension of the existing knowledge about the amorphous state.Abstract:
A series of semiconducting samples with noncrystalline structure was prepared by the thermal degradation of phenol formaldehyde resin at different heat treatment temperatures. DC measurements on these organic materials yield an interesting extension of the existing knowledge about the amorphous state. The most important result is the fact that pyrolyzed phenol formaldehyde resins show a temperature dependence on conductivity which is characteristic for the Mott hopping mechanism and identical with that of layers made by evaporating Ge, Si, GaAs or carbon. Hence it does not seem to be the chemical composition that is determining the mechanism of electrical conduction in amorphous solids but only the physical structure.read more
Citations
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Journal ArticleDOI
DC and AC conductivity in hopping electronic systems
R.M. Hill,A.K. Jonscher +1 more
TL;DR: In this article, various theories of dc and ac conductivity in materials with hopping electronic charge carriers are critically examined in the light of the available experimental evidence, showing that none of the existing theories being capable of accounting adequately for the observed behaviour.
Journal ArticleDOI
Single-site pyrrolic-nitrogen-doped sp 2 -hybridized carbon materials and their pseudocapacitance
Kesong Tian,Junyan Wang,Ling Cao,Yang Wei,Wanchun Guo,Shuhu Liu,Wei Li,Fengyan Wang,Xueai Li,Zhaopeng Xu,Zhen-Bo Wang,Haiyan Wang,Yanglong Hou +12 more
TL;DR: This work reports the preparation of single pyrrolic N-doped carbon materials (SPNCMs) with a tunable nitrogen content from 0 to 4.22 at.% based on a strategy of low-temperature dehalogenation-induced and subsequent alkaline-activated pyrolysis of 3-halogenated phenol-3-aminophenol-formaldehyde (X-APF) co-condensed resins.
Journal ArticleDOI
Variable range hopping revisited: the case of an exponential distribution of localized states
TL;DR: In this article, a numerical model of single-phonon hopping transport within distributions of localized electronic states is presented, showing that many transport data for amorphous semiconductors and polymers are consistent with exponential tail state distributions rather than with Mott's hypothesis of an energy-independent distribution near the Fermi level.
Journal ArticleDOI
Memory switching in glow discharge polymerized thin films
L. F. Pender,R. J. Fleming +1 more
TL;DR: In this paper, two distinct forms of memory switching have been observed in thin films (500-4000 A) of glow discharge polymerized styrene, acetylene, benzene, and aniline.
References
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Journal ArticleDOI
Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors
E. A. Davis,Nevill Mott +1 more
TL;DR: In this article, the experimental evidence concerning the density of states in amorphous semiconductors and the ranges of energy in which states are localized is reviewed; this includes d.c and a.c. conductivity, drift mobility and optical absorption.
Journal ArticleDOI
The effect of crosslinking on the formation of glasslike carbons from thermosetting resins
Erich Fitzer,W. Schäfer +1 more
TL;DR: In this paper, the pyrolysis of polyfurfuryl alcohol and phenolic polymers leading to glass-like carbon is studied in detail, and the effect of cross-linking of the polymers is shown by the modification with formaldehyde as well as by comparison with oxidized polyphenylene oxide.
Journal ArticleDOI
Electrical conduction in amorphous silicon and germanium
TL;DR: In this paper, the same level and temperature dependence of electrical conductivity in the interval 60-300 °K was observed for amorphous silicon layers and germanium layers.
Journal ArticleDOI
Pre‐exponential Factor in Semiconducting Organic Substances
TL;DR: In this article, a three-constant equation of the following form applies: σ(T) = ωσ0′ exp(E/ε/ε) exp(−E/δ/ε), where T 0 is a new constant, the "characteristic temperature" of the substance.