Journal ArticleDOI
Pyrolysis mechanisms of methoxy substituted α-O-4 lignin dimeric model compounds and detection of free radicals using electron paramagnetic resonance analysis
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TLDR
In this paper, the pyrolysis of methoxy substituted α-O-4 dimeric phenolic compounds at 500°C using a Frontier Lab micro-pyrolyzer was investigated.About:
This article is published in Journal of Analytical and Applied Pyrolysis.The article was published on 2014-11-01. It has received 65 citations till now. The article focuses on the topics: Radical & Homolysis.read more
Citations
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Journal ArticleDOI
Radical-Based C-C Bond-Forming Processes Enabled by the Photoexcitation of 4-Alkyl-1,4-dihydropyridines.
TL;DR: This photochemical dual‐reactivity profile was used to trigger radical‐based carbon–carbon bond‐forming processes, including nickel‐catalyzed cross‐coupling reactions.
Wood chemistry: fundamentals and applications.
TL;DR: The authors examines the basic principles of wood chemistry and its potential applications to pulping and papermaking, wood and wood waste utilization, pulping by-products for production of chemicals and energy, and biomass conversion.
Journal ArticleDOI
Lignin Valorization through Thermochemical Conversion: Comparison of Hardwood, Softwood and Herbaceous Lignin
TL;DR: In this paper, milled wood lignin (MWL) and organosolv lignins isolated from red oak (hardwood), loblolly pine (softwood) and corn stover (herbaceous biomass) were characterized by TGA, elemental analyzer, GPC, FTIR, 2D-HSQC NMR, and then pyrolyzed in the absence and presence of a zeolite catalyst.
Journal ArticleDOI
Catalytic fast pyrolysis of biomass with noble metal-like catalysts to produce high-grade bio-oil: Analytical Py-GC/MS study
TL;DR: In this article, four kinds of noble metal-like catalysts W2C/AC, W2N/AC and W2AC/AC were used for catalytic fast pyrolysis of biomass to upgrade the fuel properties of biomass pyrolyncolysis vapors.
Book ChapterDOI
Mechanistic Understanding of Thermochemical Conversion of Polymers and Lignocellulosic Biomass
TL;DR: A critical review of the elementary reactions involved in the pyrolysis of polyolefins to various products is presented in this article along with an elucidation of detailed kinetic modeling.
References
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Book
Wood Chemistry: Fundamentals and Applications
TL;DR: The authors examines the basic principles of wood chemistry and its potential applications to pulping and papermaking, wood and wood waste utilization, pulping by-products for production of chemicals and energy, and biomass conversion.
Journal ArticleDOI
Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues
TL;DR: In this article, slow pyrolysis of agricultural residues such as olive husk, corncob and tea waste at high temperature (950-1250 K) in a cylindrical reactor batch reactor was investigated.
Journal ArticleDOI
Mechanisms of liquefaction and pyrolysis reactions of biomass
TL;DR: In the liquefaction process, the micellar-like broken down fragments produced by hydrolysis are degraded to smaller compounds by dehydration, dehydrogenation, deoxygenation and decarboxylation as mentioned in this paper.
Book
Modern Molecular Photochemistry of Organic Molecules
TL;DR: In this paper, a theory of molecular organic photochemistyr is presented, and a generalization of the Photochemistry of organic Molecules Index is presented for the first time.
Journal ArticleDOI
Catalytic pyrolysis of individual components of lignocellulosic biomass
TL;DR: In this paper, the authors report on the catalytic pyrolysis of switchgrass and its three main components (cellulose, hemicellulose and lignin) over H-ZSM5 catalyst.