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Rational confinement engineering of MOF-derived carbon-based electrocatalysts toward CO2 reduction and O2 reduction reactions

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The article was published on 2021-10-14 and is currently open access. It has received 36 citations till now. The article focuses on the topics: Electrocatalyst & Carbon.

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High-Throughput Computational Screening of Metal–Organic Frameworks as High-Performance Electrocatalysts for CO2RR

TL;DR: In this paper , the authors proposed that the polarity of the coordination bonds between the metal atoms and the coordination atoms in ligands has a significant impact on the activation of CO2 molecules, and the selectivity of HCOOH mainly depends on the adsorption energy difference between HCOO and COOH.
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Pt3Ni alloy catalyst coupled with three-dimensional nitrogen-doped graphene for enhancing the alkaline hydrogen evolution

TL;DR: In this article , a Pt3Ni/3DNG catalyst with three-dimensional N-doped graphene nanoparticles was used for enhancing the alkaline hydrogen evolution reaction (HER), which achieved an exceptional alkaline HER activity with a mass activity 14 times that of commercial 40 wt.% Pt/C at 70 mV.
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Electrocatalytic CO2 conversion on metal-organic frameworks derivative electrocatalysts

TL;DR: In this article , metal-organic frameworks (MOFs)-derived nanomaterials offer several competencies as viable electrocatalysts for converting notorious CO2 to value-added products with realistic electrochemical activity and stability without additional CO2 emission.
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Flexible Smart Wearable Co@C@Carbon Fabric for Efficient Electromagnetic Shielding, Thermal Therapy, and Human Movement Monitoring

TL;DR: In this paper , an unprecedented strategy is proposed to combine a metal-organic framework and a fabric substrate for electromagnetic interference shielding, which can effectively prevent electromagnetic pollution, relieve joint pain, and detect the human movement and possesses wide application prospects.
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CoN<sub>4</sub>C<sub><i>x</i></sub> Electrocatalyst for CO<sub>2</sub> Reduction to CO by the Solid Polymer Electrolyte Electrolysis

TL;DR: In this paper , a new compound prepared from poly(4-vinylpyridine), Co(NO3)2, and Ketjenblack (KB, Lion Special Chemical) by partial pyrolysis in Ar at 673 K, Co(PV4Py)/KB(673 K), effectively catalyzed electroreduction of CO2 to CO in the solid polymer electrolyte (SPE) electrolysis gas cell without using carbonate solutions.
References
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Journal ArticleDOI

The Chemistry and Applications of Metal-Organic Frameworks

TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Graphene and Graphene Oxide: Synthesis, Properties, and Applications

TL;DR: An overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.
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Single-atom catalysts: a new frontier in heterogeneous catalysis.

TL;DR: Recent advances in preparation, characterization, and catalytic performance of SACs are highlighted, with a focus on single atoms anchored to metal oxides, metal surfaces, and graphene, offering the potential for applications in a variety of industrial chemical reactions.
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Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles.

TL;DR: This Review will compare the results obtained from different systems and try to give a picture on how different types of metal species work in different reactions and give perspectives on the future directions toward better understanding of the catalytic behavior of different metal entities in a unifying manner.
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Heterogeneous single-atom catalysis

TL;DR: A review of single-atom catalysts can be found in this paper, where the authors discuss the utility of SACs in a broad scope of industrially important reactions and highlight the advantages these catalysts have over those presently used.
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