Journal ArticleDOI
Rhodium-catalyzed intramolecular [4 + 2] cycloadditions of alkynyl halides.
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TLDR
Cationic rhodium(I)-catalyzed intramolecular [4 + 2] cycloadditions of diene-tethered alkynyl halides were found to occur in good yields and could be transformed into a variety of products that are difficult or impossible to obtain via directcycloaddition.About:
This article is published in Organic Letters.The article was published on 2005-11-22. It has received 45 citations till now. The article focuses on the topics: Cycloaddition & Intramolecular force.read more
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Haloalkynes: a powerful and versatile building block in organic synthesis.
Wanqing Wu,Huanfeng Jiang +1 more
TL;DR: This Account highlights some of the recent progress on the development of efficient and practical synthetic methods involving haloalkyne reagents in the laboratory and in others around the world, which showcase the synthetic power of haloalkynes for rapid assembly of complex molecular structures.
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Silver-Catalyzed Csp−H and Csp−Si Bond Transformations and Related Processes
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Enantioselective phase-transfer-catalyzed intramolecular aza-Michael reaction: effective route to pyrazino-indole compounds.
Patent
Novel macrocyclic inhibitors of hepatitis c virus replication
Scott D. Seiwert,Lawrence M. Blatt,Andrews Steven W,Pierre Martin,Schumacher Andreas,Bradley R. Barnett,C. Todd Eary,Kaus Robert,Timothy Kercher,Weidong Liu,Michael Lyon,Paul J. Nichols,Bin Wang,Tarek Sammakia,Kennedy April L,Jiang Yutong +15 more
TL;DR: In this paper, the authors provide compounds of the general Formulae (I) through general Formula (VIII), as well as compositions, including pharmaceutical compositions, comprising a subject compound.
Journal ArticleDOI
An alkynyliodide cycloaddition strategy for the construction of iodoisoxazoles
TL;DR: The thermally promoted cycloaddition between alkynyliodides and nitrile oxides is reported, which offers excellent regioselectivity and a broad scope with respect to both the iodoalkynes and chloro-oximes.
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Related Papers (5)
Nickel-catalyzed intramolecular [4+2] dienyne cycloadditions: an efficient new method for the synthesis of polycycles containing cyclohexa-1,4-dienes
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