Journal ArticleDOI
Selective oxidation of aldehydes to carboxylic acids with sodium chlorite-hydrogen peroxide
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TLDR
In this article, the authors propose a method for the Oxydation de cinnamaldehydes, benzaldehyde, furfural, pyridine carbaldehyde-4, thiophene carbaldehyde, 2 pyrrolecarbaldehyde-2, alcenals, dans l'acetonitrile et dans different solvants alcooliques.Abstract:
Oxydation de cinnamaldehydes, benzaldehydes, furfural, pyridinecarbaldehyde-4, thiophenecarbaldehyde-2, pyrrolecarbaldehyde-2, alcenals, dans l'acetonitrile et dans differents solvants alcooliquesread more
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Journal ArticleDOI
Production of amorphadiene in yeast, and its conversion to dihydroartemisinic acid, precursor to the antimalarial agent artemisinin
Patrick J. Westfall,Douglas J. Pitera,Jacob R. Lenihan,Diana Eng,Frank X. Woolard,Rika Regentin,Tizita Horning,Hiroko Tsuruta,David J. Melis,Andrew Owens,Scott Fickes,Don Diola,Kirsten R. Benjamin,Jay D. Keasling,Michael D. Leavell,Derek McPhee,Neil Stephen Renninger,Jack D. Newman,Chris J. Paddon +18 more
TL;DR: Progress is described toward the goal of developing a supply of semisynthetic artemisinin based on production of the art Artemisinin precursor amorpha-4,11-diene by fermentation from engineered Saccharomyces cerevisiae, and its chemical conversion to dihydroartemisinic acid, which can be subsequently converted to artemis inin.
Journal ArticleDOI
Oxidation of Primary Alcohols to Carboxylic Acids with Sodium Chlorite Catalyzed by TEMPO and Bleach
Mangzhu Zhao,Jing Li,Eiichi Mano,Zhiguo Song,David M. Tschaen,Edward J. J. Grabowski,Paul J. Reider +6 more
Journal ArticleDOI
A novel chromium trioxide catalyzed oxidation of primary alcohols to the carboxylic acids
Mangzhu Zhao,Jing Li,Zhiguo Song,Richard Desmond,D. M. Tschaen,Edward J. J. Grabowski,Paul J. Reider +6 more
TL;DR: In this article, a novel CrO 3 catalyzed oxidation of primary alcohols to the carboxylic acids was reported, and the oxidation proceeds smoothly with only 1−2 mol % of CrO3 and 2.5 equivalents of H 5 IO 6 in wet MeCN.
Journal ArticleDOI
1-N-Iminosugars: Potent and Selective Inhibitors of β-Glycosidases
TL;DR: A series of 1-N-iminosugars were synthesized to supply the need for glycosidase inhibitors that are both highly potent and selective for β-glycosidases, designed on the basis of the transition-state model of the β-glucosidase reaction.
Journal ArticleDOI
Giant regular polyhedra from calixarene carboxylates and uranyl
Sara Pasquale,Sara Sattin,Eduardo C. Escudero-Adán,Marta Martínez-Belmonte,Javier de Mendoza +4 more
TL;DR: Novel, self-assembled cages are reported, using the conical-shaped carboxylic acid derivatives of calix[4]arene and calix-arene as ligands, and the uranyl cation UO(2)2+ as a metallic counterpart, which coordinates with three carboxylates at the equatorial plane, giving rise to hexagonal bipyramidal architectures.
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