Journal ArticleDOI
Selective Oxidative Phenol Coupling by Iron Catalysis.
TLDR
This synopsis describes the selectivity challenges inherent in oxidative coupling reactions while at the same time presents the mechanistic-driven strategy employed to confront them.Abstract:
The iron-catalyzed oxidative coupling of phenols has emerged as a powerful method for preparing complex phenolic frameworks from simple and readily available compounds. This synopsis describes the selectivity challenges inherent in oxidative coupling reactions while at the same time presents our mechanistic-driven strategy employed to confront them.read more
Citations
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Journal ArticleDOI
Synthetic Applications of Oxidative Aromatic Coupling – from Biphenols to Nanographenes
TL;DR: Analysis of the progress achieved in this field since 2013 reveals that many groups have contributed by pushing the boundary of structural possibilities, expanding into surface‐assisted (cyclo)dehydrogenation, and developing new reagents.
Journal ArticleDOI
Syntheseanwendungen der oxidativen aromatischen Kupplung – von Biphenolen zu Nanographenen
Journal ArticleDOI
Dehydrogenative Anodic C‐C Coupling of Phenols Bearing Electron Withdrawing Groups
TL;DR: A metal‐free, electrosynthetic method is presented that enables the direct dehydrogenative coupling reactions of phenols carrying electron‐withdrawing groups for the first time, and is efficient, practical, and thereby environmentally friendly, as production of waste is minimized.
Journal ArticleDOI
Copper-Complex-Catalyzed Asymmetric Aerobic Oxidative Cross-Coupling of 2-Naphthols: Enantioselective Synthesis of 3,3'-Substituted C1 -Symmetric BINOLs.
Jin-Miao Tian,Ai-Fang Wang,Ju-Song Yang,Xiao-Jing Zhao,Yong-Qiang Tu,Yong-Qiang Tu,Shu-Yu Zhang,Zhi-Min Chen +7 more
TL;DR: A novel chiral 1,5-N,N-bidentate ligand based on a spirocyclic pyrrolidine oxazoline backbone has been designed and prepared, generating a series of C1-symmetric chiral BINOL derivatives in high enantioselectivity and good yield.
Journal ArticleDOI
Biocatalytic oxidative cross-coupling reactions for biaryl bond formation
TL;DR: In this article , a biocatalytic method for cross-coupling of biaryl C-H bonds was presented. But the method is not suitable for the formation of sterically hindered biaryl bonds.
References
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Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Journal ArticleDOI
Aryl-aryl bond formation one century after the discovery of the Ullmann reaction.
Journal ArticleDOI
Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?
Journal ArticleDOI
Atroposelective Synthesis of Axially Chiral Biaryl Compounds
Gerhard Bringmann,Anne J. Price Mortimer,Paul A. Keller,Mary J. Gresser,James Garner,Matthias Breuning +5 more
TL;DR: This Review classifies strategies in the asymmetric synthesis of axially chiral biaryl compounds according to their underlying concepts and critically evaluates their scope and limitations with reference to selected model reactions and applications.
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