Journal ArticleDOI
Solar Energy Conversion with Fluorescent Collectors
A. Goetzberger,W. Greubel +1 more
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TLDR
In this article, a new principle for solar energy conversion is proposed and evaluated theoretically, and the optical path length in a triangular collector is computed, which offers the advantage of separating the various fractions of light and converting them with solar cells with different bandgaps.Abstract:
A new principle for solar energy conversion is proposed and evaluated theoretically. Collection and concentration of direct and diffuse radiation is possible by the use of a stack of transparent sheets of material doped with fluorescent dyes. High efficiency of light collection can be achieved by light guiding and special design of collectors. The optical path length in a triangular collector is computed. In combination with solar cells this type of collector offers the advantage of separating the various fractions of light and converting them with solar cells with different bandgaps. Theoretical conversion efficiency under optimum conditions is 32% for a system with four semiconductors. Thermal energy conversion offers several advantages over conventional collectors: High temperature and efficiency even under weak illumination, separation of heat transport and radiation collection, low thermal mass. Thermal efficiency is computed to be between 42% and 60%. Very attractive appear hybrid systems for generation of thermal and electric energy. An estimate of the economics of electricity generation shows that due to the concentration costs can be much lower than possible today. With the use of only silicon cells the breakeven point of $0.5/W is almost reached. Practical difficulties to be solved are: Synthesis of dyes with stringent requirements, identification of plastic materials with high transparency and development of solar cells with higher bandgaps.read more
Citations
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Journal ArticleDOI
Multiple dyes containing luminescent solar concentrators with enhanced absorption and efficiency
Cheng Liu,Baojun Li +1 more
TL;DR: In this paper, the fabrication and characterization of luminescent solar concentrators (LSCs) that contain multiple dyes was reported. And the three-dye LSC had a power conversion efficiency of 1.40% with an optical concentration ratio of 1 2.
Journal ArticleDOI
From steam engine to solar cells: can thermodynamics guide the development of future generations of photovoltaics?
TL;DR: In this article, the authors argue that thermodynamics has played a singular role in the development of virtually all energy technologies to date, and that it also has a role to play in the understanding and design of solar cell operation, particularly looking toward the future, high-efficiency solar cells.
Journal ArticleDOI
Optical and thermal spectroscopic studies of luminescent dye doped poly(methyl methacrylate) as solar concentrator
TL;DR: In this article, a luminescent solar concentrator was prepared that was based on a bulk sheet of poly(methyl methacrylate) doped with different luminecent dyes (K1, K27, and Lpero) during the polymerization process.
Journal ArticleDOI
“N-alkyl diketopyrrolopyrrole-based fluorophores for luminescent solar concentrators: Effect of the alkyl chain on dye efficiency”
TL;DR: In this article, a luminescent solar concentrators made of poly(methyl methacrylate) (PMMA) thin films doped with six new diketopyrrolopyrrole (DPP) fluorophores obtained in good yields by using simple N-alkylation and direct C H arylation synthetic strategies.
References
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The Theory and Practice of Scintillation Counting
J. B. Birks,F. W. K. Firk +1 more
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Luminescent greenhouse collector for solar radiation.
Willes H. Weber,John J Lambe +1 more
Journal ArticleDOI
Limitations and Possibilities for Improvement of Photovoltaic Solar Energy Converters: Part I: Considerations for Earth's Surface Operation
TL;DR: In this paper, seven factors limiting the performance of photovoltaic solar energy converters are listed and explained, which can be classified into basic and technology-decided limitations.
Journal ArticleDOI
High‐efficiency Ga1−xAlxAs–GaAs solar cells
Jerry M. Woodall,H. Hövel +1 more
TL;DR: In this paper, a homojunction solar cell consisting of pGa1−xAlxAs−pGaAs-n GaAs was used to achieve power conversion efficiency of over 16% (corrected for contact area) measured in sunlight for air mass 1 at sea level, while efficiencies of 19-20% for an air mass value of 2 or more.
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