Journal ArticleDOI
Strong anion receptor-assisted boron-based Mg electrolyte with wide electrochemical window and non-nucleophilic characteristic
Huimin Xu,Huimin Xu,Zhonghua Zhang,Zili Cui,Aobing Du,Chenglong Lu,Shanmu Dong,Jun Ma,Xinhong Zhou,Guanglei Cui +9 more
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TLDR
In this article, a strong anion receptor-assisted Mg-ion electrolyte is presented, which is synthesized from tris(2H-hexafluoroisopropyl) borate (THFPB) and MgO in 1,2-dimethoxyethane (DME).About:
This article is published in Electrochemistry Communications.The article was published on 2017-10-01. It has received 51 citations till now. The article focuses on the topics: Electrolyte & Electrochemical window.read more
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Toward Highly Reversible Magnesium–Sulfur Batteries with Efficient and Practical Mg[B(hfip)4]2 Electrolyte
Zhirong Zhao-Karger,Runyu Liu,Wenxu Dai,Zhenyou Li,Thomas Diemant,B. P. Vinayan,Christian Bonatto Minella,Xingwen Yu,Arumugam Manthiram,R. Jürgen Behm,Mario Ruben,Mario Ruben,Maximilian Fichtner +12 more
TL;DR: In this article, the authors demonstrate that magnesium tetrakis(hexafluoroisopropyloxy) borate Mg[B(hfip)4]2 satisfies a multitude of requirements for an efficient and practical electrolyte, including high anodic stability, high ionic conductivity, and excellent long-term Mg cycling stability with a low polarization.
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Challenges and Recent Progress on Key Materials for Rechargeable Magnesium Batteries
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Rechargeable Magnesium Batteries using Conversion-Type Cathodes: A Perspective and Minireview
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Teaching an old dog new tricks: new directions in fundamental and applied closo-carborane anion chemistry.
TL;DR: New directions in the fundamental and applied chemistry of the closo-carborane anions and N-heterocyclic carbenes as well as some related chemistry with the dicarbolide ion are covered.
References
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Journal ArticleDOI
Prototype systems for rechargeable magnesium batteries
Doron Aurbach,Z. Lu,Alex Schechter,Yossi Gofer,Haim Gizbar,R. Turgeman,Yair Cohen,M. Moshkovich,Elena Levi +8 more
TL;DR: Rechargeable Mg battery systems that show promise for applications comprise electrolyte solutions based on Mg organohaloaluminate salts, and MgxMo 3S4 cathodes, into which Mg ions can be intercalated reversibly, and with relatively fast kinetics.
Journal ArticleDOI
Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries
Zhenhua Sun,Jingqi Zhang,Lichang Yin,Guangjian Hu,Ruopian Fang,Hui-Ming Cheng,Hui-Ming Cheng,Feng Li +7 more
TL;DR: A conductive porous vanadium nitride nanoribbon/graphene composite accommodating the catholyte as the cathode of a lithium–sulfur battery provides strong anchoring for polysulfides and fastpolysulfide conversion.
Journal ArticleDOI
Metallic anodes for next generation secondary batteries.
TL;DR: This review mainly focuses on the electrochemical behaviors and technical issues related to metallic Li anode materials as well as other metallic anodes materials such as alkali (Na) and alkaline earth (Mg) metals, including Zn and Al when these metal anodes were employed for various types of secondary batteries.
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Nonaqueous Electrochemistry of Magnesium Applications to Energy Storage
TL;DR: In this paper, an ambient temperature rechargeable magnesium battery based on organic electrolytes and positive electrodes capable of reversible intercalation of Mg+2 ions is discussed. But the number of combinations of solvent, solute, and inter-calation cathode which give reasonable battery performance is much more limited for Mg than for alkali metals.
Journal ArticleDOI
Structure and compatibility of a magnesium electrolyte with a sulphur cathode
Hee Soo Kim,Timothy S. Arthur,Gary D. Allred,Jaroslav Zajicek,John G. Newman,Alexander E. Rodnyansky,Allen G. Oliver,William C. Boggess,John Muldoon +8 more
TL;DR: Kim et al. as discussed by the authors presented a non-nucleophilic electrolyte from hexamethyldisilazide magnesium chloride and aluminium trichloride, and showed its compatibility with a sulphur cathode.