Journal ArticleDOI
Synthesis and structure of four- and five-coordinated gaseous oxohalides of molybdenum(VI) and tungsten(VI)
Brian G. Ward,Fred E. Stafford +1 more
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This article is published in Inorganic Chemistry.The article was published on 1968-12-01. It has received 43 citations till now. The article focuses on the topics: Molybdenum & Tungsten.read more
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Reactions of tungsten(vi) and molybdenum(v) chlorides, and tungsten(vi) and molybdenum(vi) oxychlorides, with azoxybenzene
TL;DR: In this paper, the reaction between MoCl5 or MoOCl4 and azoxybenzene gives, after extraction with methylene chloride-ethanol mixture, the complex [trans-MoOCl 4(OC2H5)]− [C12H10N2H]+.
Journal ArticleDOI
Molybdenum Difluoride Dioxide, MoO2F2
TL;DR: A preliminary model of the structure of MoO(2)F(2), which has a triangular columnar structure with three fluorine bridges between the three molybdenum atoms, is obtained from powder data.
Journal ArticleDOI
Infrared Spectroscopic and Theoretical Studies on the OMF2 and OMF (M = Cr, Mo, W) Molecules in Solid Argon
Rui Wei,Qingnuan Li,Yu Gong,Yu Gong,Lester Andrews,Zongtang Fang,K. Sahan Thanthiriwatte,Monica Vasiliu,David A. Dixon +8 more
TL;DR: A bonding analysis showed that the OMF2 molecules have highly ionic M-F bonds, which have triple-bond character for all three metals.
Journal ArticleDOI
Some reactions of iron (III) and chromium (III) fluorides with oxides
N.C. Cabeldu,B. Leng,J.H. Moss +2 more
TL;DR: In this paper, the reaction of CrF 3 with oxides is compared, and the reactions observed being generally similar, with higher valency elements complete fluorine exchange did not always occur and oxyfluorides were formed.
Journal ArticleDOI
Characterization of Silica Supported Transition‐Metal Oxide Catalysts by Luminescence Spectroscopy
M. F. Hazenkamp,G. Blasse +1 more
TL;DR: In this paper, the luminescence properties of some silica-supported transition-metal (Mo, W, Nb, Re) oxide catalysts are reported under dehydrated conditions and at low temperatures.
References
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713. The stretching frequencies of metal–oxygen double bonds
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The Electron Diffraction Investigation of Sulfur Monochloride, Sulfur Dichloride, Sulfur Trioxide, Thionyl Chloride, Sulfuryl Chloride, Vanadium Oxytrichloride, and Chromyl Chloride
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Infrared and raman spectra of chromyl chloride
TL;DR: In this paper, the infrared spectrum of CrO 2 Cl 2, a deep red liquid, has been measured from 120-3000 cm −1, where six Raman lines have been obtained by excitation with the D -lines of potassium.
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Infrared Absorption Spectra of Chromyl Fluoride and Chromyl Chloride
TL;DR: In this paper, the infrared spectrum of gaseous chromyl fluoride and chromyl chloride has been investigated and the observed transitions have been assigned on the basis of a tetrahedral model of C2v symmetry.
Journal ArticleDOI
Infrared spectra of the vapors above sulfuric and deuteriosulfuric acids
TL;DR: In this article, the infrared absorption spectra in the range 4000 to 400/cm of the vapors above liquid H2SO4, 1:1 H2-SO4 D2SO 4, and D2 SO4 were measured and assigned to the respective gaseous molecules as well as equilibrium concentrations of SO3.
Related Papers (5)
Infrared Spectra of Some Gaseous Molybdenum Oxides and Oxyhalides
Terry V. Iorns,Fred E. Stafford +1 more