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Journal ArticleDOI

Synthesis, characterization and degradation of ABA block copolymer of l-lactide and ε-caprolactone

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TLDR
Degradable ABA block copolymers were synthesized by the bulk copolymerization of PCL pre-polymers and l -lactide with stannous octanoate as the catalyst at 120°C for 120 h as discussed by the authors.
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This article is published in Polymer Degradation and Stability.The article was published on 2000-05-11. It has received 147 citations till now. The article focuses on the topics: Lactide & Caprolactone.

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Plasma Surface Modification of Biodegradable Polymers: A Review

TL;DR: A critical overview on recent advances in plasma-assisted surface modification of biodegradable polymers can be found in this paper, where the authors present a critical overview of recent advances.
Journal ArticleDOI

Degradation and Healing Characteristics of Small-Diameter Poly(ε-Caprolactone) Vascular Grafts in the Rat Systemic Arterial Circulation

TL;DR: In this paper, small-diameter vascular grafts made of PCL nanofibers were compared with expanded polytetrafluoroethylene (ePTFE) grafts.
Journal ArticleDOI

In vitro and in vivo degradation of non-woven materials made of poly(ε-caprolactone) nanofibers prepared by electrospinning under different conditions

TL;DR: In this article, the aim was to prepare nonwoven materials from a biodegradable polymer, poly(e-caprolactone) (PCL) by electrospinning.
Journal ArticleDOI

In vivo biocompatibilty and degradation behavior of elastic poly(l-lactide-co-ε-caprolactone) scaffolds

TL;DR: The scaffolds applied in this study were found to exhibit excellent tissue compatibility to SMCs and might be very useful for vascular tissue engineering.
Journal ArticleDOI

Polylactic acid (PLA) synthesis and modifications: a review

TL;DR: In this article, various methods of synthesizing polycondensation and ring-opening polymerization and modifying properties of polylactic acid (PLA), which may be used as biomaterials, such as a drug carrier in a drug delivery system, as a cell scaffold and suture in tissue engineering, and as packaging materials in packaging engineering field.
References
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Journal ArticleDOI

Biodegradable polymers for use in surgery—polyglycolic/poly(actic acid) homo- and copolymers: 1

TL;DR: In this paper, the historical development of polyglycolic acid (PGA) and polylactic acid (PLA) polymers and copolymers for use in surgery is set down.
Journal ArticleDOI

Biodegradable poly(lactic acid) polymers

TL;DR: A biological in vitro method for determining the degradation of poly(lactic acids) indicates, in accordance with expectations, that poly(dl-lactic acid) degrades at a faster rate than L(+) lactic acid.
Journal ArticleDOI

Macromolecular engineering of polylactones and polylactides. 4. Mechanism and kinetics of lactide homopolymerization by aluminum isopropoxide

TL;DR: The ring-opening polymerization of lactides initiated by aluminium isopropoxide in toluene at 70°C proceeds through a "coordination-insertion" mechanism and selective rupture of the acyl oxygen bond of the monomer.
BookDOI

Contemporary Topics in Polymer Science

TL;DR: Muggins et al. as discussed by the authors presented the Division of polymer chemistry award to Maurice L Muggins for the Structures of Collagen and discussed the effects of exposure of blood coagulation factors and platelets to synthetic polymers.
Journal ArticleDOI

Biodegradable lactone copolymers. I: Characterization and mechanical behavior of ε-caprolactone and lactide copolymers

TL;DR: In this article, the effect of the comonomer ratio on the thermal and mechanical properties of the copolymers was investigated by size-exclusion chromatography (SEC), differential scanning calorimetry (DSC), nuclear magnetic resonance (NMR) spectrometry, and tensile testing.
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