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Synthesis of 3d metallic single-molecule magnets

Guillem Aromí, +1 more
- 26 Jan 2006 - 
- Vol. 38, Iss: 23, pp 1-67
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This article is published in ChemInform.The article was published on 2006-01-26. It has received 1933 citations till now.

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Compartmental Schiff-base ligands--a rich library of tectons in designing magnetic and luminescent materials.

TL;DR: 3d-3d' and 3d-4f complexes are useful precursors in designing heterotrimetallic systems with relevance in molecular magnetism.
Journal ArticleDOI

What is not required to make a single molecule magnet.

TL;DR: The theory that can be applied and the principles of the computational approach for representative mononuclear complexes are demonstrated and small units may subsequently be employed as building blocks for the controlled assembly of larger and maximally anisotropic single molecule magnets.
Journal ArticleDOI

Theoretical support for using the Δf(r) descriptor

TL;DR: In this article, the Δf(r) descriptor is regarded through three different theoretical points of view: its relations with the Fukui functions, its links with the covalent interaction energy, and finally its compliance with the Principle of Maximum Hardness.
Journal ArticleDOI

A neutron diffraction study of the stannite-kesterite solid solution series

TL;DR: In this paper, a combination of neutron and X-ray powder diffraction was used to determine the average neutron scattering length of the cation sites in stannite, kesterite and Cu 2 Fe 1−x Zn x SnS 4 solid solutions.
References
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Journal ArticleDOI

Magnetic bistability in a metal-ion cluster

TL;DR: In this article, it was shown that the magnetization of the Mn12 cluster is highly anisotropic and the magnetisation relaxation time becomes very long below a temperature of 4 K, giving rise to pronounced hysteresis.
Journal ArticleDOI

Quantum computing in molecular magnets

TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.
Journal ArticleDOI

Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level

TL;DR: Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property and a significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs.
Journal ArticleDOI

High-spin molecules: [Mn12O12(O2CR)16(H2O)4]

TL;DR: In this paper, the electrochemical and magnetochemical properties of [Mn 12 O 12 (O 2 CPh) 16 (H 2 O) 4 ] (3), its solvate 3.

Quantum computing in molecular magnets

TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.
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