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Synthesis of 3d metallic single-molecule magnets
Guillem Aromí,Euan K. Brechin +1 more
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This article is published in ChemInform.The article was published on 2006-01-26. It has received 1933 citations till now.read more
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Microwave assisted synthesis in coordination chemistry
Alba Pons-Balagué,María José Heras Ojea,Marisol Ledezma-Gairaud,Daniel Reta Mañeru,Simon J. Teat,José Sánchez Costa,Guillem Aromí,E. Carolina Sañudo +7 more
TL;DR: In this paper, the synthesis assisted by microwave radiation has proven to be an excellent tool for the achievement of new structural types of polynuclear transition metal complexes such as Mn, Co and Ni.
Journal ArticleDOI
Ligand effect and cooperative role of metal ions on the DNA cleavage efficiency of mono and binuclear Cu(II) macrocyclic ligands complexes
TL;DR: Both the binuclear complexes cleaved supercoiled DNA efficiently to Form III (linearized DNA) in the presence of H2O2, indicating that nuclearity is a crucial parameter in oxidative cleavage.
Journal ArticleDOI
Substitution of lysine with glutamic acid at position 193 in bovine CYP11A1 significantly affects protein oligomerization and solubility but not enzymatic activity.
TL;DR: A single amino acid mutation, K193E, could be identified which leads not only to a higher solubility of CYP11A1 as well as a 4-fold improved expression rate, but also lowers the oligomerization of the protein while its activity is only slightly decreased.
Journal ArticleDOI
Superconductivity and the Van Hove Scenario
Julien Bok,J. Bouvier +1 more
TL;DR: In this article, the role of Van Hove singularities in superconductivity was discussed and the existence of VHs near the Fermi level in the cuprates is now well established.
Journal ArticleDOI
Mn7 species with an S = 29/2 ground state: high-frequency EPR studies of a species at the classical/quantum spin interface.
Zhenxing Wang,Johan van Tol,Taketo Taguchi,Matthew R. Daniels,George Christou,Naresh S. Dalal +5 more
TL;DR: A fast Fourier transform analysis of the sharp spectral features and the low temperature EPR spectra suggests that more than one spin state are involved; these features have been well reproduced by computer simulations.
References
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Journal ArticleDOI
Magnetic bistability in a metal-ion cluster
TL;DR: In this article, it was shown that the magnetization of the Mn12 cluster is highly anisotropic and the magnetisation relaxation time becomes very long below a temperature of 4 K, giving rise to pronounced hysteresis.
Journal ArticleDOI
Quantum computing in molecular magnets
TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.
Journal ArticleDOI
Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
TL;DR: Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property and a significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs.
Journal ArticleDOI
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
Roberta Sessoli,Hui Lien Tsai,Ann R. Schake,Sheyi Wang,John B. Vincent,Kirsten Folting,Dante Gatteschi,George Christou,David N. Hendrickson +8 more
TL;DR: In this paper, the electrochemical and magnetochemical properties of [Mn 12 O 12 (O 2 CPh) 16 (H 2 O) 4 ] (3), its solvate 3.
Quantum computing in molecular magnets
TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.