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Synthesis of 3d metallic single-molecule magnets
Guillem Aromí,Euan K. Brechin +1 more
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This article is published in ChemInform.The article was published on 2006-01-26. It has received 1933 citations till now.read more
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Mechanical properties of silicon nitride-based ceramics and its use in structural applications at high temperatures
TL;DR: In this paper, the room temperature and high-temperature properties of Si 3 N 4 based ceramics are discussed and described in more detail, and a variety of interesting properties can be specifically designed to produce a given behavior profile.
Journal ArticleDOI
Ground state spin-switching via targeted structural distortion: twisted single-molecule magnets from derivatised salicylaldoximes.
TL;DR: The deliberate chemically-induced structural distortion of the [Mn6] molecule allows the isolation of analogous family members displaying remarkably different magnetic properties and this in turn allows for a rare semi-quantitative magneto-structural correlation which enables prediction of the magnetic properties of new family members.
Journal ArticleDOI
Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism
Yong-Kai Deng,Hai-Feng Su,Jia-Heng Xu,Wenguang Wang,Mohamedally Kurmoo,Shui-Chao Lin,Yuan-Zhi Tan,Jiong Jia,Di Sun,Di Sun,Lan-Sun Zheng +10 more
TL;DR: The elucidation of a hierarchical step-by-step formation from monomer to heptamer to nonadecamer (Mn19) satisfying the relation 1 + Σn6n, where n is the ring number of the Brucite structure using high-resolution electrospray ionization mass spectrometry (HRESI-MS).
Journal ArticleDOI
Shedding Light on the Single-Molecule Magnet Behavior of Mononuclear DyIII Complexes
Daniel Aravena,Eliseo Ruiz +1 more
TL;DR: It is found that most existing mononuclear zero-field SMMs adopting a heteroleptic coordination mode mixing neutral and anionic ligands present the same pattern in the electrostatic potential induced by their ligands, with a lower potential island related to the presence of neutral ligands inside a high potential background related with anionic groups.
Journal ArticleDOI
Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries
Yong-Ning Zhou,Jun Ma,Enyuan Hu,Xiqian Yu,Lin Gu,Kyung-Wan Nam,Liquan Chen,Zhaoxiang Wang,Xiao-Qing Yang +8 more
TL;DR: The cation mixing caused by migration of molybdenum ions at higher oxidation state provides the benefits of reducing the c expansion range in the early stage of charging and suppressing the structure collapse at high voltage charge.
References
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Journal ArticleDOI
Magnetic bistability in a metal-ion cluster
TL;DR: In this article, it was shown that the magnetization of the Mn12 cluster is highly anisotropic and the magnetisation relaxation time becomes very long below a temperature of 4 K, giving rise to pronounced hysteresis.
Journal ArticleDOI
Quantum computing in molecular magnets
TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.
Journal ArticleDOI
Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
TL;DR: Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property and a significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs.
Journal ArticleDOI
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
Roberta Sessoli,Hui Lien Tsai,Ann R. Schake,Sheyi Wang,John B. Vincent,Kirsten Folting,Dante Gatteschi,George Christou,David N. Hendrickson +8 more
TL;DR: In this paper, the electrochemical and magnetochemical properties of [Mn 12 O 12 (O 2 CPh) 16 (H 2 O) 4 ] (3), its solvate 3.
Quantum computing in molecular magnets
TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.