Journal ArticleDOI
tert-Butyldimethylsilyldihalomethyllithium as a dihalomethylene dianion synthon. 1,3-Rearrangement and 1,4-rearrangement of silyl group from carbon to oxide
TLDR
One-pot synthesis of R 1 CH(OSiMe 2 - t -Bu)CX 2 CH(OH)R 2 (X=Cl, Br) successive addition of two different aldehydes (R 1 CHO and R 2 CHO) has been achieved starting from tert -butyldimethylsilyldihalomethyllithium as mentioned in this paper.About:
This article is published in Tetrahedron.The article was published on 1996-01-08. It has received 58 citations till now. The article focuses on the topics: Carbanion & Ether.read more
Citations
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Natural product synthesis using multicomponent reaction strategies.
B. Barry Touré,Dennis G. Hall +1 more
TL;DR: The preparation of urea by Wöhler constituted a landmark achievement in organic chemistry, and it laid the ground for the early days of target-oriented organic synthesis, a task deemed inconceivable by early practitioners.
Journal ArticleDOI
Small Heterocycles in Multicomponent Reactions
Benjamin H. Rotstein,Benjamin H. Rotstein,Serge Zaretsky,Vishal Rai,Vishal Rai,Andrei K. Yudin +5 more
TL;DR: This paper presents a meta-analyses of the proton-probes of Na6(SO4)2, Na4, and Na4 of the nucleus of the H2O2 molecule and shows clear patterns in the response of these two mechanisms to each other.
Journal ArticleDOI
The role of 1,3-dithianes in natural product synthesis
TL;DR: Foubelo et al. as mentioned in this paper studied carbanions, organolithium compounds, and dithioacetal moiety in the tetrahedron of the Tetrarch.
References
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Journal ArticleDOI
Asymmetric hetero-Diels-Alder reaction catalyzed by a chiral organoaluminum reagent
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Triethylborane-Induced Hydrodehalogenation of Organic Halides by Tin Hydrides
Katsukiyo Miura,Yoshifumi Ichinose,Kyoko Nozaki,Keigo Fugami,Koichiro Oshima,Kiitiro Utimoto +5 more
TL;DR: The reduction of organic halides with tributyltin hydride in the presence of a catalytic amount of triethylborane has been studied in this paper, and the reduction of alkenyl halides and alkyl bromides with n-Bu3SnH-Et3B system was not so effective.
Journal ArticleDOI
Umsetzung metallierter Trimethylsilylformaldehyd-thioacetale mit Carbonylverbindungen. Eine einfache Methode großer Anwendungsbreite zur Herstellung von Keten-thioacetalen
TL;DR: In this paper, a simple method of broad applicability for the preparation of ketene thioacetals was proposed for the Preparation of Ketene Thioacetal (KTE) compounds.