Journal ArticleDOI
Tetraazacyclophanes by Palladium-Catalyzed Aromatic Amination. Geometrically Defined, Stable, High-Spin Diradicals
TLDR
In this article, neutral tetraazacyclophanes were prepared in a one-step palladium-catalyzed amination reaction and simple oxidation of these materials creates dication diradicals that are stable at room temperature.About:
This article is published in Organic Letters.The article was published on 1999-11-25. It has received 95 citations till now. The article focuses on the topics: Amination & Dication.read more
Citations
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Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications
TL;DR: The historical development and current state of the art in this rapidly expanding field of research is summarized, which has become one of the key exploration areas of modern heterocyclic chemistry.
Journal ArticleDOI
Organic mixed-valence compounds: a playground for electrons and holes.
TL;DR: The goal of this Review is to give an overview of the last decade in organic mixed valence chemistry and to elucidate its impact on modern functional materials chemistry.
Journal ArticleDOI
Polymers for electronics and spintronics
Piotr Bujak,Irena Kulszewicz-Bajer,Malgorzata Zagorska,Vincent Maurel,Ireneusz Wielgus,Adam Pron +5 more
TL;DR: This critical review is devoted to semiconducting and high spin polymers which are of great scientific interest in view of further development of the organic electronics and the emerging organic spintronic fields.
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The Complementary Competitors: Palladium and Copper in C-N Cross-Coupling Reactions
TL;DR: In this article, a discussion of cross-coupling chemistry of these two metals can be performed within a common mechanistic paradigm, helping to elucidate the key factors governing the behavior of the transition-metal complexes involved.
References
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Journal ArticleDOI
Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation
Journal ArticleDOI
Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C−N Bond Formation with a Commercial Ligand
TL;DR: The reactions of aryl bromides with amines occurs at room temperature when using Pd(0) and P(t-Bu)(3) in a 1:1 ratio, and the reactions ofAryl chlorides occur atRoom temperature or 70 degrees C.
Journal ArticleDOI
Hole transport in solid solutions of a diamine in polycarbonate
M. Stolka,J. F. Yanus,D. M. Pai +2 more
TL;DR: In this article, a solution solide de N,N'-diphenyl N, N'-bis(methyl-3 phenyl) biphenyl-1, 1' diamine-4, 4' dans un polycarbonate de bisphenol A
Journal ArticleDOI
Trap-controlled hopping transport
D. M. Pai,J. F. Yanus,M. Stolka +2 more
TL;DR: In this paper, the polyvinyl carbazole dope avec la N,N'-diphenyl, N, N'-bis(methyl-3 phenyl) biphenyl-1,1' diamine-4,4'